Synthesis of Poly (Butyl Methacrylate/Butyl Acrylate) Highly Absorptive Resin Using Glow Discharge Electrolysis

LI Yan(李岩); YAO Mengqi(姚萌奇); LIAO Ruirui(廖瑞瑞); YANG Wu(杨武); GAO Jinzhang(高锦章); REN Jie(任杰)

doi:10.1088/1009-0630/16/8/08

Plasma Science and Technology > 2014 > 16(8): 777-781. > DOI: 10.1088/1009-0630/16/8/08

LI Yan(李岩), YAO Mengqi(姚萌奇), LIAO Ruirui(廖瑞瑞), YANG Wu(杨武), GAO Jinzhang(高锦章), REN Jie(任杰). Synthesis of Poly (Butyl Methacrylate/Butyl Acrylate) Highly Absorptive Resin Using Glow Discharge Electrolysis[J]. Plasma Science and Technology, 2014, 16(8): 777-781. DOI: 10.1088/1009-0630/16/8/08

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Synthesis of Poly (Butyl Methacrylate/Butyl Acrylate) Highly Absorptive Resin Using Glow Discharge Electrolysis

Chemistry & Chemical Engineering College, Northwest Normal University, Key Lab of Bioelectrochemtry & Environmental Analysis of Gansu, Lanzhon 730070, China

Funds: supported in part by the Basic Project of Science and Research of Colleges and Universities of Gansu Province, China (5001-109), the Natural Science Foundation of Gansu Province, China (Nos. 1010 RJZA015, 096RJZA120)

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Received Date: August 07, 2013

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Abstract

Abstract

A highly absorptive resin poly (butyl methacrylate (BMA)-co-butyl acrylate (BA)) was prepared by emulsion polymerization, which was initiated by glow discharge electrolysis plasma (GDEP). The effects of discharge voltage, discharge time, monomer ratio and the amounts of cross- linking agent were examined and discussed in detail. The chemical structure of the obtained resin was characterized by means of attenuated total reflectance Fourier transform infrared spectroscopy, thermogravimetric analysis, and scanning electron microscopy. The optimal conditions were obtained as: discharge voltage was 600 V, discharge time was 8 min, the ratios of BMA:BA being 2:1 for chloroform and 3:1 for xylene, with 2% N, N’-methylenebis. Under optimal conditions, the oil absorbency was 70 g/g for chloroform and 46 g/g for xylene. Moreover, the absorptive dynamical behavior of the resulting resin was also investigated.
- glow discharge electrolysis plasma emulsion polymerization,
- resin

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References (21)

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