Determination of Iron in Water Solution by Time-Resolved Femtosecond Laser-Induced Breakdown Spectroscopy

Sergey S. GOLIK; Alexey A. ILYIN; Michael Yu. BABIY; Yulia S. BIRYUKOVA; Vladimir V. LISITSA; Oleg A. BUKIN

doi:10.1088/1009-0630/17/11/16

Plasma Science and Technology > 2015 > 17(11): 975-978. > DOI: 10.1088/1009-0630/17/11/16

Sergey S. GOLIK, Alexey A. ILYIN, Michael Yu. BABIY, Yulia S. BIRYUKOVA, Vladimir V. LISITSA, Oleg A. BUKIN. Determination of Iron in Water Solution by Time-Resolved Femtosecond Laser-Induced Breakdown Spectroscopy[J]. Plasma Science and Technology, 2015, 17(11): 975-978. DOI: 10.1088/1009-0630/17/11/16

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Determination of Iron in Water Solution by Time-Resolved Femtosecond Laser-Induced Breakdown Spectroscopy

1Far Eastern Federal University, 8 Suhanova Str., Vladivostok 690950, Russia 2Institute of Automation and Control Processes, Far Eastern Branch, Russian Academy of Sciences, 5 Radio Str., Vladivostok 690041, Russia

Funds: supported by the Russian Science Foundation (agreement #14-50-00034) (measurements of limit of detection), Russian Foundation for Basic Research (NK 15-32-20878/15) obtained in the frame of “Organization of Scientific Research” in the Far Eastern Federal University supported by Ministry of Education and Science of Russian Federation

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Received Date: April 19, 2015

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Abstract

Abstract

The influence of the energy of femtosecond laser pulses on the intensity of Fe I (371.99 nm) emission line and the continuous spectrum of the plasma generated on the surface of Fe3+ water solution by a Ti: sapphire laser radiation with pulse duration <45 fs and energies up to 7 mJ is determined. A calibration curve was obtained for Fe3+ concentration range from 0.5 g/L to the limit of detection in water solution, and its saturation was detected for concentrations above 0.25 g/L, which is ascribed to self-absorption. The 3σ-limit of detection obtained for Fe in water solution is 2.6 mg/L in the case of 7 mJ laser pulse energy. It is found that an increase of laser pulse energy insignificantly affects on LOD in the time-resolved LIBS and leads to a slight improvement of the limit of detection.
- femtosecond laser-induced breakdown spectroscopy,
- LIBS,
- femtosecond plasma,
- iron,
- analysis of water,
- atomic emission spectroscopy,
- limit of detection

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References

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