Spectral characteristic of laser-induced plasma in soil

The spectral characteristic of laser-induced plasma in soil was studied in this work, laser-induced breakdown spectroscopy was used to analyze the spectral characteristic of plasma under the condition of different time delays and irradiances. Moreover, the time evolution characteristics of plasma temperature and electron density were discussed. Within the time delay range of 0–5 μs, the spectral intensity of the characteristic lines of Si I: 288.158 nm, Ti I: 336.126 nm, Al I: 394.400 nm and Fe I: 438.354 nm of the four main elements in two kinds of national standard soil decayed exponentially with time. The average lifetime of the spectral lines was nearly 1.56 μs. Under the condition of different time delays, the spectral intensity of Pb I: 405.78 nm in soil increased linearly with laser energy. However, the slope between the spectral intensity and laser energy decreased exponentially with the increase in time delay, from 4.91 to 0.99 during 0–5 μs. The plasma temperature was calculated by the Boltzmann plot method and the electron density was obtained by inversion of the full width at half maximum of the spectrum. The plasma temperature decreased from 8900 K to 7800 K and the electron density decreased from 1.5×10¹⁷ cm⁻³ to 7.8×10¹⁶ cm⁻³ in the range of 0–5 μs.