Colorimetric quantification of aqueous hydrogen peroxide in the DC plasma-liquid system

Renze YU (俞仁泽); Zhaoyuan LIU (刘钊源); Jiao LIN (林娇); Xinyi HE (何心怡); Linsheng LIU (刘林生); Qing XIONG (熊青); Qiang CHEN (陈强); Kostya (Ken) OSTRIKOV (欧思聪)

doi:10.1088/2058-6272/abf47f

Plasma Science and Technology > 2021 > 23(5): 55504-055504. > DOI: 10.1088/2058-6272/abf47f

Renze YU (俞仁泽), Zhaoyuan LIU (刘钊源), Jiao LIN (林娇), Xinyi HE (何心怡), Linsheng LIU (刘林生), Qing XIONG (熊青), Qiang CHEN (陈强), Kostya (Ken) OSTRIKOV (欧思聪). Colorimetric quantification of aqueous hydrogen peroxide in the DC plasma-liquid system[J]. Plasma Science and Technology, 2021, 23(5): 55504-055504. DOI: 10.1088/2058-6272/abf47f

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Colorimetric quantification of aqueous hydrogen peroxide in the DC plasma-liquid system

¹ Shenzhen Research Institute of Xiamen University, Institute of Electromagnetics and Acoustics, Fujian Provincial Key Laboratory of Plasma and Magnetic Resonance, Key Laboratory of Electromagnetic Wave Science and Detection Technology, Xiamen University, Xiamen 361005, People's Republic of China
² State Key Laboratory of Electrical Insulation and Power Equipment, Centre for Plasma Biomedicine, Xi'an Jiaotong University, Xi'an 710049, People's Republic of China
³ College of electronic engineering, Guangxi Normal University, Guilin 541004, People's Republic of China
⁴ State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, Chongqing 400044, People's Republic of China
⁵ School of Chemistry and Physics, Queensland University of Technology, Brisbane, QLD 4000, Australia

Funds: Q Chen thanks National Natural Science Foundation of China (No. 52077185) and the Basic Research Program of Science and Technology of Shenzhen, China (No. JCYJ20190809162617137) for partial financial support. L Liu thanks for the financial supports from the Basic Ability Promotion Project for Young and Middle-Aged Teachers in Universities of Guangxi (No. 2018KY0083) and Doctoral Scientific Research Fund of Guangxi Normal University (No. 2017BQ019). Q Xiong thanks for the financial supports from National Natural Science Foundation of China (No. 11975061), the Technology Innovation and Application Development Project of Chongqing (No. cstc2019jscx-msxmX0041), the Construction Committee Project of Chongqing (No. 2018-1-3-6), and the Fundamental Research Funds for the Central Universities (No. 2019CDQYDQ034). K Ostrikov thanks the Australian Research Council (ARC) for partial support.

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Received Date: January 28, 2021
Revised Date: March 29, 2021
Accepted Date: March 31, 2021

Graphical Abstract

Abstract

Abstract

The quantification of hydrogen peroxide (H₂O₂) generated in the plasma-liquid interactions is of great importance, since the H2O2 species is vital for the applications of the plasma-liquid system. Herein, we report on in situ quantification of the aqueous H₂O₂ (H₂O_2aq) using a colorimetric method for the DC plasma-liquid systems with liquid as either a cathode or an anode. The results show that the H₂O_2aqyield is 8–12 times larger when the liquid acts as a cathode than when the liquid acts as an anode. The conversion rate of the gaseous OH radicals to H₂O_2aq is 4–6 times greater in the former case. However, the concentrations of dissolved OH radicals for both liquid as cathode and anode are of the same order of tens of nM.
- plasma-liquid interactions,
- hydrogen peroxide,
- OH radical,
- atmospheric-pressureplasma

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References (74)

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