Development of miniaturized SAF-LIBS with high repetition rate acousto-optic gating for quantitative analysis

Fei CHEN; Jiajia HOU; Gang WANG; Yang ZHAO; Jiaxuan LI; Shuqing WANG; Lei ZHANG; Wanfei ZHANG; Xiaofei MA; Zhenrong LIU; Xuebin LUO; Wangbao YIN; Suotang JIA

doi:10.1088/2058-6272/ac8511

Plasma Science and Technology > 2023 > 25(1): 015510. > DOI: 10.1088/2058-6272/ac8511

Fei CHEN, Jiajia HOU, Gang WANG, Yang ZHAO, Jiaxuan LI, Shuqing WANG, Lei ZHANG, Wanfei ZHANG, Xiaofei MA, Zhenrong LIU, Xuebin LUO, Wangbao YIN, Suotang JIA. Development of miniaturized SAF-LIBS with high repetition rate acousto-optic gating for quantitative analysis[J]. Plasma Science and Technology, 2023, 25(1): 015510. DOI: 10.1088/2058-6272/ac8511

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Development of miniaturized SAF-LIBS with high repetition rate acousto-optic gating for quantitative analysis

1.
State Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, People's Republic of China
2.
Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan 030006, People's Republic of China
3.
School of Physics and Optoelectronic Engineering, Xidian University, Xi'an 710071, People's Republic of China
4.
Shanxi Xinhua Chemical Defense Equipment Research Institute Co., Ltd., Taiyuan 030006, People's Republic of China
5.
School of Science, North University of China, Taiyuan 030051, People's Republic of China
6.
National Energy R & D Center of Petroleum Refining Technology (RIPP, SINOPEC), Beijing 100083, People's Republic of China

More Information

Corresponding author:
Lei ZHANG, E-mail: k1226@sxu.edu.cn (Lei Zhang)

Wangbao YIN, E-mail: ywb65@sxu.edu.cn (Wangbao Yin)
Received Date: February 16, 2022
Revised Date: July 25, 2022
Accepted Date: July 27, 2022
Available Online: December 05, 2023
Published Date: November 10, 2022

Graphical Abstract

Abstract

Abstract

The self-absorption effect in laser-induced breakdown spectroscopy (LIBS) reduces the accuracy of quantitative measurement results. The self-absorption-free LIBS (SAF-LIBS) has been proved to directly capture the optically thin plasma spectra by setting an appropriate exposure time. In this work, a novel SAF-LIBS technique with high repetition rate acousto-optic gating is developed, in which an acousto-optic modulator is used as the shutter to diffract the optically thin fluorescence, and a high repetition rate laser is used to produce quasi-continuous plasmas to enhance the integral spectral intensity, so that the CCD spectrometer can replace an intensified CCD (ICCD) and echelle spectrometer in SAF-LIBS. Experimental results show that the average absolute prediction error of aluminum is reduced to 0.18%, which is equivalent to that of traditional SAF-LIBS. This technique not only effectively shields continuous background radiation and broadened spectral lines in optically thick plasma, but also has advantages of miniaturization, low cost, convenience and reliability.

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Acknowledgments

This work is supported by National Key R & D Program of China (No. 2017YFA0304203); National Energy R & D Center of Petroleum Refining Technology (RIPP, SINOPEC); Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China (IRT_17R70); National Natural Science Foundation of China (Nos. 61975103, 61875108, 61775125 and 11434007); Major Special Science and Technology Projects in Shanxi (No. 201804D131036); 111 Project (No. D18001); Fund for Shanxi '1331KSC'.

References (25)

References

[1]	Sarkar A, Alamelu D and Aggarwal S K 2012 Opt. Laser Technol. 44 30 doi: 10.1016/j.optlastec.2011.05.010
[2]	Body D and Chadwick B L 2001 Rev. Sci. Instrum. 72 1625 doi: 10.1063/1.1338486
[3]	Labutin T A et al 2014 Spectrochim. Acta B 99 94 doi: 10.1016/j.sab.2014.06.021
[4]	Zhang L et al 2015 Spectrochim. Acta B 113 167 doi: 10.1016/j.sab.2015.09.021
[5]	Liu F et al 2018 Sensors 18 705 doi: 10.3390/s18030705
[6]	Lu C P et al 2011 Acta Phys. Sin. 60 045206(in Chinese) doi: 10.7498/aps.60.045206
[7]	Mateo M P, Nicolas G and Yañez A 2007 Appl. Surf. Sci. 254 868 doi: 10.1016/j.apsusc.2007.08.043
[8]	Radziemski L J 2002 Spectrochim. Acta B 57 1109 doi: 10.1016/S0584-8547(02)00052-6
[9]	Konjević N 1997 Phys. Rep. 316 339 doi: 10.1016/S0370-1573(98)00132-X
[10]	Sibaiya L 1939 Proc. Indian Acad. Sci. A 9 219 doi: 10.1007/BF03046464
[11]	Player M A, Watson J and De Freitas J M O 2000 Influence of self-absorption on the performance of laser-induced breakdown spectroscopy (LIBS) 2000 Proc. SPIE 4076, Optical Diagnostics for Industrial Applications (Glasgow) (Proc. SPIE)
[12]	El Sherbini A M et al 2005 Spectrochim. Acta B 60 1573 doi: 10.1016/j.sab.2005.10.011
[13]	Bredice F et al 2006 Spectrochim. Acta B 61 1294 doi: 10.1016/j.sab.2006.10.015
[14]	Mansour S A M 2015 Opt. Photonics J. 5 79 doi: 10.4236/opj.2015.53007
[15]	Li T Q et al 2019 Anal. Chim. Acta 1058 39 doi: 10.1016/j.aca.2019.01.016
[16]	Aguilera J A, Bengoechea J and Aragón C 2003 Spectrochim. Acta B 58 221 doi: 10.1016/S0584-8547(02)00258-6
[17]	Moon H Y et al 2009 Spectrochim. Acta B 64 702 doi: 10.1016/j.sab.2009.06.011
[18]	Horňáčková M et al 2012 Pre-study of silicon and aluminum containing materials for further zeolites CF-LIBS analysis Proc. Contributed Papers (Prague: MATFYZPRESS) pp 134–9
[19]	Konjević N, Ivković M and Jovićević S 2010 Spectrochim. Acta B 65 593 doi: 10.1016/j.sab.2010.03.009
[20]	D'Angelo C A et al 2015 J. Quant. Spectrosc. Radiat. Transfer 164 89 doi: 10.1016/j.jqsrt.2015.05.014
[21]	Shah M L et al 2013 Plasma Sci. Technol. 15 546 doi: 10.1088/1009-0630/15/6/11
[22]	Hou J J et al 2017 Opt. Express 25 23024 doi: 10.1364/OE.25.023024
[23]	Hou J J et al 2019 Opt. Express 27 32184 doi: 10.1364/OE.27.032184
[24]	Sakka T et al 2011 Rev. Sci. Instrum. 82 023112 doi: 10.1063/1.3544021
[25]	Pořízka P et al 2014 Rev. Sci. Instrum. 85 073104 doi: 10.1063/1.4890337

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