| Citation: |
Guangjia WANG, Shidong FANG, Baoguo LIN, Chengzhu ZHU, Jie SHEN. Mechanistic study on 4, 4'-sulfonylbis removal with CO2/Ar gas-liquid DBD plasma[J]. Plasma Science and Technology, 2024, 26(10): 105501. DOI: 10.1088/2058-6272/ad5118
|
In this study, a single dielectric barrier discharge (DBD) coaxial reactor was used to degrade 4, 4'-sulfonylbis (TBBPS) in water using greenhouse gas (CO2) and argon as the carrier gases. The investigation focused on CO2 conversion, reactive species formation, gas-liquid mass transfer mechanism, and degradation mechanism of TBBPS during the discharge plasma process. With the decrease of CO2/Ar ratio in the process of plasma discharge, the emission spectrum intensity of Ar, CO2 and excited reactive species was enhanced. This increase promoted collision and dissociation of CO2, resulting in a series of chemical reactions that improved the production of reactive species such as ·OH, 1O2, H2O2 and O3. These reactive species initiated a sequence of reactions with TBBPS. Results indicated that at a gas flow rate of 240 mL/min with a CO2/Ar ratio of 1:5, both the highest CO2 conversion rate (17.76%) and TBBPS degradation rate (94.24%) were achieved. The degradation mechanism was elucidated by determining types and contents of reactive species present in treatment liquid along with analysis of intermediate products using liquid chromatography-mass spectrometry techniques. This research provides novel insights into carbon dioxide utilization and water pollution control through dielectric barrier discharge plasma technology.
This work was supported jointly by National Natural Science Foundation of China (No. 51877208), Anhui Provincial Key R&D Programmers (No. 202004a07020047).
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