Abstract: To date, the selection of the magnetic field line used to match the chamfered inner and outer channel walls in a magnetically shielded Hall thruster has not been quantitatively studied. Hence, an experimental study was conducted on a 1.35 kW magnetically shielded Hall thruster with a xenon propellant. Different magnetic field lines were chosen, and corresponding tangentially matched channel walls were manufactured and utilized. The results demonstrate that high performance and a qualified anti-sputtering effect cannot be achieved simultaneously. When the magnetic field lines that match the chamfered wall have a strength at the channel centerline of less than 12% of the maximum field strength, the channel wall can be adequately protected from ion sputtering. When the magnetic field lines have a strength ratio of 12%–20%, the thruster performance is high. These findings provide the first significant quantitative design reference for the match between the magnetic field line and chamfered channel wall in magnetically shielded Hall thrusters.