利用大气压下介质阻挡放电等离子体方法处理工业垃圾渗沥液
Plasma Treatment of Industrial Landfill Leachate by Atmospheric Pressure Dielectric Barrier Discharges
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摘要: 本文介绍了利用大气压下介质阻挡放电等离子体处理垃圾渗沥液的方法。研究发现工作频率, 工作电压, 气流量和处理时间等放电参数对于工业垃圾渗沥液中氨氮的去除有重要的影响。增加处理时间对氨氮的去除效率有明显增加 (达到了83%), 并且渗沥液也从深灰黑色变成无色透明的液体, 因此, 大气压下介质阻挡放电等离子体方法可以有效降解垃圾渗沥液。介质阻挡放电的电流电压波形揭示了不同放电参数条件下的放电特性。原子发射光谱测量显示, 在O2介质阻挡放电等离子体中产生的氧化物质在氧化有机物和无机物, 以及渗沥液的脱色效果中起了重要作用。Abstract: An dielectric barrier discharge (DBD) system in atmospheric pressure utilized for the treatment of industrial landfill leachate is reported. The discharge parameters, such as the operating frequency, gas flow rate, and treating duration, were found to affect significantly the removal of ammonia nitrogen (AN) in industrial landfill leachate. An increase in treating duration leads to an obvious increase in the removal efficiency of AN (up to 83%) and the leachate color changed from deep grey-black to transparent. Thus the dielectric barrier discharges in atmospheric pressure could degrade the landfill leachate effectively. Typical waveforms of both applied voltage and discharge current were also presented for analyzing the discharge processes under different discharge parameters. Optical emission spectra measurements indicate that oxidation species generated in oxygen DBD plasma play a crucial role in removing AN, oxidizing organic and inorganic substances and decolorizing the landfill leachate.
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