Surface Modifiation of PBO Fibers for Composites by Coaxial Atmospheric Dielectric Barrier Discharge (PLA-PLA)

HU Qianqian (胡倩倩); XU Jinzhou (徐金洲); ZHOU Zhenxing (周振兴); ZHANG Jing (张菁)

doi:10.1088/1009-0630/15/5/07

Plasma Science and Technology > 2013 > 15(5): 429-434. > DOI: 10.1088/1009-0630/15/5/07

HU Qianqian (胡倩倩), XU Jinzhou (徐金洲), ZHOU Zhenxing (周振兴), ZHANG Jing (张菁). Surface Modifiation of PBO Fibers for Composites by Coaxial Atmospheric Dielectric Barrier Discharge (PLA-PLA)[J]. Plasma Science and Technology, 2013, 15(5): 429-434. DOI: 10.1088/1009-0630/15/5/07

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Surface Modifiation of PBO Fibers for Composites by Coaxial Atmospheric Dielectric Barrier Discharge (PLA-PLA)

1 College of Materials Science and Engineering, Donghua University, Shanghai 201620, China 2 Department of Applied Physics, College of Science, Donghua University, Shanghai 201620, China

Funds: supported by Shanghai Composite Company and partially by National Natural Science Foundation of China (No. 10875146)

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Abstract

Abstract

In this work, the surface modifition of poly (1, 4-phenylene-cis-benzobisoxazole) (PBO) fibers by O₂/Ar coaxial atmospheric dielectric barrier discharge was investigated, as well as the interfacial adhesion properties of modified PBO fibers/epoxy composites. The results indicated that the contact angle decreased remarkably from 84.7± to 63.5± after 3 min O₂/Ar plasma treatment. SEM and AFM images showed that the surface of the treated PBO fibers became rather rough. In addition, XPS results suggested that the polar functional group (O=C- O) was introduced on the surface of the treated PBO fiber. The interfacial adhesion test showed that the interfacial shear strength (IFSS) and the interlaminar shear strength (ILSS) increased significantly by 63.54% and 130%, respectively. Moreover, the excellent tensile property of the PBO fibres was well preserved.