Adhesion Improvement of Zirconium Coating on Polyurethane Modified by Plasmas

GAO Yi (高毅); HAO Xiaofei (郝晓飞); LIU Jiwei (刘际伟)

doi:10.1088/1009-0630/18/2/10

Plasma Science and Technology > 2016 > 18(2): 157-161. > DOI: 10.1088/1009-0630/18/2/10

GAO Yi (高毅), HAO Xiaofei (郝晓飞), LIU Jiwei (刘际伟). Adhesion Improvement of Zirconium Coating on Polyurethane Modified by Plasmas[J]. Plasma Science and Technology, 2016, 18(2): 157-161. DOI: 10.1088/1009-0630/18/2/10

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Adhesion Improvement of Zirconium Coating on Polyurethane Modified by Plasmas

Institute of Chemical Material, China Academy of Engineering Physics, Mianyang 621900, China

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Received Date: April 15, 2015

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Abstract

Abstract

In order to improve the adhesion of the middle frequency magnetic sputtered zirco?nium coating on a polyurethane film, an anode layer source was used to pretreat the polyurethane film with nitrogen and oxygen ions. SEMs and AFM roughness profiles of treated samples and the contrast groups were obtained. Besides, XPS survey spectrums and high resolution spec?trums were also investigated. The adhesion test revealed that ion bombardment could improve the adhesion to the polyurethane coating substrate. A better etching result of oxygen ions versus nitrogen predicts a higher bonding strength of zirconium coating on polyurethane and, indeed, the highest bonding strengths are for oxygen ion bombardment upto 13.3 MPa. As demonstrated in X-ray photoelectron spectroscopy, the oxygen ion also helps to introduce more active groups, and, therefore, it achieves a high value of adhesion strength.
- anode layer source,
- polyurethane (PU),
- zirconium coating,
- adhesion,
- func?tional groups

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