Decomposition of Potent Greenhouse Gases SF6, CF4 and SF5CF3 by Dielectric Barrier Discharge

ZHANG Renxi (张仁熙); WANG Jingting (王婧婷); CAO Xu (曹栩); HOU Huiqi (侯惠奇)

doi:10.1088/1009-0630/18/4/10

Plasma Science and Technology > 2016 > 18(4): 388-393. > DOI: 10.1088/1009-0630/18/4/10

ZHANG Renxi (张仁熙), WANG Jingting (王婧婷), CAO Xu (曹栩), HOU Huiqi (侯惠奇). Decomposition of Potent Greenhouse Gases SF₆, CF₄ and SF₅CF₃ by Dielectric Barrier Discharge[J]. Plasma Science and Technology, 2016, 18(4): 388-393. DOI: 10.1088/1009-0630/18/4/10

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Decomposition of Potent Greenhouse Gases SF₆, CF₄ and SF₅CF₃ by Dielectric Barrier Discharge

Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP), Depart?ment of Environmental Science & Engineering, Fudan University, Shanghai 200433, China

Funds: supported by National Natural Science Foundation of China (Nos. 20507004, 21577023)

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Received Date: August 30, 2015

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For their distinguished global warming potential (GWP100) and long atmosphere lifespan, CF₄, SF₆ and SF₅CF₃ were significant in the field of greenhouse gas research. The details of discharging character and the optimal parameter were discussed by using a Dielectric Barrier Discharge (DBD) reactor to decompose these potent greenhouse gases in this work. The results showed that SF6 could be decomposed by 92% under the conditions of 5 min resident time and 3000 V applied voltage with the partial pressure of 2.0 kPa, 28.2 kPa, and 1.8 kPa for SF₆, air and water vapor, respectively. 0.4 kPa CF₄ could be decomposed by 98.2% for 4 min resident time with 30 kPa Ar added. The decomposition of SF5CF3 was much more effective than that of SF₆ and CF4 and moreover, 1.3 kPa SF₅CF₃, discharged with 30 kPa O₂, Ar and air, could not be detected when the resident time was 80 s, 40 s, and 120 s, respectively. All the results indicated that DBD was a feasible technique for the abatement of potent greenhouse gases.
- dielectric barrier discharge,
- SF5CF3,
- CF4,
- SF6

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Decomposition of Potent Greenhouse Gases SF₆, CF₄ and SF₅CF₃ by Dielectric Barrier Discharge

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Decomposition of Potent Greenhouse Gases SF₆, CF₄ and SF₅CF₃ by Dielectric Barrier Discharge