Analytical study of seashell using laser-induced breakdown spectroscopy

Ying LI (李颖); Yanhong GU (谷艳红); Ying ZHANG (张莹); Yuandong LI (李远东); Yuan LU (卢渊)

doi:10.1088/2058-6272/19/2/025501

Plasma Science and Technology > 2017 > 19(2): 25501-025501. > DOI: 10.1088/2058-6272/19/2/025501

Ying LI (李颖), Yanhong GU (谷艳红), Ying ZHANG (张莹), Yuandong LI (李远东), Yuan LU (卢渊). Analytical study of seashell using laser-induced breakdown spectroscopy[J]. Plasma Science and Technology, 2017, 19(2): 25501-025501. DOI: 10.1088/2058-6272/19/2/025501

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Analytical study of seashell using laser-induced breakdown spectroscopy

Optics and Optoelectronics Laboratory, Ocean University of China, Qingdao 266100, People’s Republic of China

Funds: This research was financially supported by National Natural Science Foundation of China (No. 41506113) and Natural Science Foundation of Shandong Province (No. ZR2014DP010).

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Received Date: April 25, 2016

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Abstract

Abstract

Seashell has been applied as an indicator for ocean research and element analysis of the seashell is used to track biological or environmental evolution. In this work, laser-induced breakdown spectroscopy (LIBS) was applied for elementary analysis of an ezo scallop-shell, and a graphite enrichment method was used as the assistance. It was found that LIBS signal intensity of Ca fluctuated less than 5%, in spite of the sampling positions, and Sr/Ca was relatedtothe shellgrowth. Asimilar variationwas also foundwhenusing adirect LIBS analysis on the shell surface, and it might be more practicable to track shell growth by investigating Sr/Ca ratio with Sr ionic line at 421.6 nm. The obtained results prove that calcium (Ca) is quali?ed as an internal reference for shell analysis, and LIBS is a potential analytical method for seashell study.
- seashell analysis,
- LIBS,
- graphite enriched process,
- Sr/Ca,
- shell growth

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References (25)

References

[1]	Moini M et al 2014 Zoo Biol. 33 285
[2]	Ries J B 2012 Nat. Geosci. 5 845
[3]	Metalpa R R et al 2011 Nat. Clim. Change 1 308
[4]	Rittschof D and Green P M 2005 Mar. Pollut. Bull. 50 369
[5]	Peharda M et al 2015 Mar. Biol. 162 1531
[6]	Klein R T, Lohmann K C and Thayer C W 1996 Geology 24 415
[7]	Freitas P et al 2005 Geochem. Geophys. Geosyst. 6 1
[8]	Gillikin D P et al 2008 Geo-Mar. Lett. 28 351
[9]	Hatch M B A, Schellenberg S A and Carter M L 2013 Palaeogeogr. Palaeoclimatol. Palaeoecol. 373 98
[10]	Richardson C A et al 2004 J. Exp. Mar. Biol. Ecol. 299 1
[11]	Gillikin D P et al 2005 Geochem. Geophys. Geosyst. 6 1
[12]	Perez-Huerta A et al 2013 PLoS One 8 e54274
[13]	Lazareth C E et al 2007 Geochim. Cosmochim. Acta 71 5369
[14]	Sano Y et al 2012 Nat. Commun. 3 761
[15]	Pinon V, Mateo M P and Nicolas G 2013 Appl. Spectrosc. Rev. 48 357
[16]	Hahn D W and Omenetto N 2010 Appl. Spectrosc. 64 335A
[17]	Barbini R et al 2002 Spectrochim. Acta B 57 1203
[18]	Lazic V et al 2007 Spectrochim. Acta B 62 30
[19]	BiY F et al 2015 Plasma Sci. Technol. 17 923
[20]	Yang G et al 2015 Plasma Sci. Technol. 17 656
[21]	Akpovo C A et al 2013 Anal. Methods 5 3956
[22]	Vitkova G et al 2012 Spectrochim. Acta B 73 1
[23]	Lu Y et al 2015 Spectrochim. Acta B 110 63
[24]	Labutin T A et al 2013 Spectrochim. Acta B 87 57
[25]	Wang Y et al 2013 Laser Technol. 37 808 (in Chinese)

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