Accurate quantitative CF-LIBS analysis of both major and minor elements in alloys via iterative correction of plasma temperature and spectral intensity

Shuxia ZHAO (赵书霞); Lei ZHANG (张雷); Jiajia HOU (侯佳佳); Yang ZHAO (赵洋); Wangbao YIN (尹王保); Weiguang MA (马维光); Lei DONG (董磊); Liantuan XIAO (肖连团); Suotang JIA (贾锁堂)

doi:10.1088/2058-6272/aa97ce

Plasma Science and Technology > 2018 > 20(3): 35502-035502. > DOI: 10.1088/2058-6272/aa97ce

Shuxia ZHAO (赵书霞), Lei ZHANG (张雷), Jiajia HOU (侯佳佳), Yang ZHAO (赵洋), Wangbao YIN (尹王保), Weiguang MA (马维光), Lei DONG (董磊), Liantuan XIAO (肖连团), Suotang JIA (贾锁堂). Accurate quantitative CF-LIBS analysis of both major and minor elements in alloys via iterative correction of plasma temperature and spectral intensity[J]. Plasma Science and Technology, 2018, 20(3): 35502-035502. DOI: 10.1088/2058-6272/aa97ce

Citation:

PDF (678 KB)

Accurate quantitative CF-LIBS analysis of both major and minor elements in alloys via iterative correction of plasma temperature and spectral intensity

1 State Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, People’s Republic of China 2 Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan 030006, People’s Republic of China

Funds: The work was financially supported by the National Key Research and Development Program of China (No. 2017YFA0304203), the Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China (No. IRT13076), National Natural Science Foundation of China (Nos. 61475093, 61378047, 61775125), the Shanxi ‘1331 Project’ Key Subjects Construction and the Major Special Science and Technology Projects in Shanxi Province (No. MD2016-01). The authors thank the State Key Lab of Power Systems for technical contribution and financial support.

More Information

Received Date: September 05, 2017

Graphical Abstract

Abstract

Abstract

The chemical composition of alloys directly determines their mechanical behaviors and application fiields. Accurate and rapid analysis of both major and minor elements in alloys plays a key role in metallurgy quality control and material classification processes. A quantitative calibration-free laser-induced breakdown spectroscopy (CF-LIBS) analysis method, which carries out combined correction of plasma temperature and spectral intensity by using a second-order iterative algorithm and two boundary standard samples, is proposed to realize accurate composition measurements. Experimental results show that, compared to conventional CF-LIBS analysis, the relative errors for major elements Cu and Zn and minor element Pb in the copper-lead alloys has been reduced from 12%, 26% and 32% to 1.8%, 2.7% and 13.4%, respectively. The measurement accuracy for all elements has been improved substantially.

FullText(HTML)

References (24)

References

[1]	Li Y et al 2017 Plasma Sci. Technol. 19 025501
[2]	Wen G H et al 2014 Plasma Sci. Technol. 16 598
[3]	Yang J H et al 2015 Spectrochim. Acta B 107 45
[4]	Ferreira E C et al 2008 Spectrochim. Acta B 63 1216
[5]	Guo M Y et al 2016 Plasma Sci. Technol. 18 661
[6]	Ciucci A et al 1999 Appl. Spectrosc. 53 960
[7]	Davari S A et al 2017 J. Anal. At. Spectrom. 32 1378
[8]	Borgiaa I et al 2000 J. Cult. Heritage. 1 281
[9]	Tognoni E et al 2007 Spectrochim. Acta B 62 1287
[10]	Bulajic D et al 2002 Spectrochim. Acta B 57 339
[11]	Colao F et al 2004 J. Anal. At. Spectrom. 19 502
[12]	Bel’kov M V et al 2005 J. Appl. Spectrosc. 72 376
[13]	Fornarini L et al 2005 Spectrochim. Acta B 60 1186
[14]	Dell’Aglio M et al 2010 Geochim. Cosmochim. Acta 74 7329
[15]	Burakov V S and Raikov S N 2007 Spectrochim. Acta B 62 217
[16]	Kolmhofer P J et al 2015 Spectrochim. Acta B 106 67
[17]	Rifai K et al 2017 Spectrochim. Acta B 134 33
[18]	Gaudiuso R et al 2012 Spectrochim. Acta B 74–75 38
[19]	El Sherbini A M et al 2005 Spectrochim. Acta B 60 1573
[20]	Burakov V S et al 2004 J. Appl. Spectrosc. 71 740
[21]	De Giacomo A 2011 Spectrochim. Acta B 66 661
[22]	Capitelli M et al 2004 Spectrochim. Acta B 59 271
[23]	De Giacomo A et al 2012 Chem. Phys. 398 233
[24]	De Giacomo A et al 2008 Spectrochim. Acta B 63 805

[1]	Shoujie LI, Ronger ZHENG, Yoshihiro DEGUCHI, Wangquan YE, Ye TIAN, Jinjia GUO, Ying LI, Yuan LU. Spectra-assisted laser focusing in quantitative analysis of laser-induced breakdown spectroscopy for copper alloys[J]. Plasma Science and Technology, 2023, 25(4): 045510. DOI: 10.1088/2058-6272/aca5f4
[2]	Yaguang MEI (梅亚光), Shusen CHENG (程树森), Zhongqi HAO (郝中骐), Lianbo GUO (郭连波), Xiangyou LI (李祥友), Xiaoyan ZENG (曾晓雁), Junliang GE (葛军亮). Quantitative analysis of steel and iron by laser-induced breakdown spectroscopy using GA-KELM[J]. Plasma Science and Technology, 2019, 21(3): 34020-034020. DOI: 10.1088/2058-6272/aaf6f3
[3]	Liuyang ZHAN (詹浏洋), Xiaohong MA (马晓红), Weiqi FANG (方玮骐), Rui WANG (王锐), Zesheng LIU (刘泽生), Yang SONG (宋阳), Huafeng ZHAO (赵华凤). A rapid classification method of aluminum alloy based on laser-induced breakdown spectroscopy and random forest algorithm[J]. Plasma Science and Technology, 2019, 21(3): 34018-034018. DOI: 10.1088/2058-6272/aaf7bf
[4]	Jiamin LIU (刘佳敏), Ding WU (吴鼎), Cailong FU (付彩龙), Ran HAI (海然), Xiao YU (于潇), Liying SUN (孙立影), Hongbin DING (丁洪斌). Improvement of quantitative analysis of molybdenum element using PLS-based approaches for laser-induced breakdown spectroscopy in various pressure environments[J]. Plasma Science and Technology, 2019, 21(3): 34017-034017. DOI: 10.1088/2058-6272/aaf821
[5]	Qingdong ZENG (曾庆栋), Fan DENG (邓凡), Zhiheng ZHU (朱志恒), Yun TANG (唐云), Boyun WANG (王波云), Yongjun XIAO (肖永军), Liangbin XIONG (熊良斌), Huaqing YU (余华清), Lianbo GUO (郭连波), Xiangyou LI (李祥友). Portable fiber-optic laser-induced breakdown spectroscopy system for the quantitative analysis of minor elements in steel[J]. Plasma Science and Technology, 2019, 21(3): 34006-034006. DOI: 10.1088/2058-6272/aadede
[6]	Li FANG (方丽), Nanjing ZHAO (赵南京), Mingjun MA (马明俊), Deshuo MENG (孟德硕), Yao JIA (贾尧), Xingjiu HUANG (黄行九), Wenqing LIU (刘文清), Jianguo LIU (刘建国). Detection of heavy metals in water samples by laser-induced breakdown spectroscopy combined with annular groove graphite flakes[J]. Plasma Science and Technology, 2019, 21(3): 34002-034002. DOI: 10.1088/2058-6272/aae7dc
[7]	Dan LUO (罗丹), Ying LIU (刘英), Xiangyu LI (李香宇), Zhenyang ZHAO (赵珍阳), Shigong WANG (王世功), Yong ZHANG (张勇). Quantitative analysis of C, Si, Mn, Ni, Cr and Cu in low-alloy steel under ambient conditions via laser-induced breakdown spectroscopy[J]. Plasma Science and Technology, 2018, 20(7): 75504-075504. DOI: 10.1088/2058-6272/aabc5d
[8]	Yangmin GUO (郭阳敏), Yun TANG (唐云), Yu DU (杜宇), Shisong TANG (唐仕松), Lianbo GUO (郭连波), Xiangyou LI (李祥友), Yongfeng LU (陆永枫), Xiaoyan ZENG (曾晓雁). Cluster analysis of polymers using laser-induced breakdown spectroscopy with K-means[J]. Plasma Science and Technology, 2018, 20(6): 65505-065505. DOI: 10.1088/2058-6272/aaaade
[9]	GUO Guangmeng (郭广盟), WANG Jie (王杰), BIAN Fang (边访), TIAN Di (田地), FAN Qingwen (樊庆文). A Hydrogel’s Formation Device for Quick Analysis of Liquid Samples Using Laser-Induced Breakdown Spectroscopy[J]. Plasma Science and Technology, 2016, 18(6): 661-665. DOI: 10.1088/1009-0630/18/6/13
[10]	HE Li’ao (何力骜), WANG Qianqian (王茜蒨), ZHAO Yu (赵宇), LIU Li (刘莉), PENG Zhong (彭中). Study on Cluster Analysis Used with Laser-Induced Breakdown Spectroscopy[J]. Plasma Science and Technology, 2016, 18(6): 647-653. DOI: 10.1088/1009-0630/18/6/11

Cited By

Cited by

Periodical cited type(3)

1.	Jin, X., Yang, G., Sun, X. et al. Discrimination of rocks by laser-induced breakdown spectroscopy combined with Random Forest (RF). Journal of Analytical Atomic Spectrometry, 2022, 38(1): 243-252. DOI:10.1039/d2ja00290f
2.	Carter, S., Clough, R., Fisher, A. et al. Atomic spectrometry update: Review of advances in the analysis of metals, chemicals and materials. Journal of Analytical Atomic Spectrometry, 2019, 34(11): 2159-2216. DOI:10.1039/c9ja90058f
3.	Fu, Y., Hou, Z., Deguchi, Y. et al. From big to strong: Growth of the Asian laser-induced breakdown spectroscopy community. Plasma Science and Technology, 2019, 21(3): 030101. DOI:10.1088/2058-6272/aaf873

Other cited types(0)

Get Citation

PDF

XML

Article views (274) PDF downloads (569) Cited by(3)

Turn off MathJax

Article Contents

Abstract

References

Accurate quantitative CF-LIBS analysis of both major and minor elements in alloys via iterative correction of plasma temperature and spectral intensity