Aqueous ruthenium detection by microwave-assisted laser-induced breakdown spectroscopy

Abu Farhan ABU KASIM; M A WAKIL; Kevin GRANT; Milton HEARN; Zeyad T ALWAHABI

doi:10.1088/2058-6272/ac6733

Plasma Science and Technology > 2022 > 24(8): 084004. > DOI: 10.1088/2058-6272/ac6733

Abu Farhan ABU KASIM, M A WAKIL, Kevin GRANT, Milton HEARN, Zeyad T ALWAHABI. Aqueous ruthenium detection by microwave-assisted laser-induced breakdown spectroscopy[J]. Plasma Science and Technology, 2022, 24(8): 084004. DOI: 10.1088/2058-6272/ac6733

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Aqueous ruthenium detection by microwave-assisted laser-induced breakdown spectroscopy

School of Chemical Engineering, The University of Adelaide, Adelaide SA 5005, Australia

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Corresponding author:
Zeyad T ALWAHABI, E-mail: zeyad.alwahabi@adelaide.edu.au
¹ The first two authors contributed equally to this work.
Received Date: December 15, 2021
Revised Date: April 10, 2022
Accepted Date: April 12, 2022
Available Online: December 10, 2023
Published Date: June 28, 2022

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Abstract

Abstract

Aqueous ruthenium was detected in real-time under ambient conditions using microwave-assisted laser-induced breakdown spectroscopy (MW-LIBS). A 10 mJ laser energy and 750 W microwave power were directed at an open liquid jet sample of ruthenium. It was observed that, for liquid flow, the coupling efficiency between the microwave and the laser-induced plasma was limited to 43%. The improvement in the ruthenium's signal-to-noise ratio with MW-LIBS, with respect to LIBS, was 76-fold. Based on MW-LIBS, the limit of detection for aqueous ruthenium was determined to be 957±84 ppb.

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Aqueous ruthenium detection by microwave-assisted laser-induced breakdown spectroscopy