Improved sensitivity on detection of Cu and Cr in liquids using glow discharge technology assisted with LIBS

Duixiong SUN; Yarui WANG; Maogen SU; Weiwei HAN; Chenzhong DONG

doi:10.1088/2058-6272/ac7639

Plasma Science and Technology > 2022 > 24(8): 084008. > DOI: 10.1088/2058-6272/ac7639

Duixiong SUN, Yarui WANG, Maogen SU, Weiwei HAN, Chenzhong DONG. Improved sensitivity on detection of Cu and Cr in liquids using glow discharge technology assisted with LIBS[J]. Plasma Science and Technology, 2022, 24(8): 084008. DOI: 10.1088/2058-6272/ac7639

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Improved sensitivity on detection of Cu and Cr in liquids using glow discharge technology assisted with LIBS

1.
Key Laboratory of Atomic and Molecular Physics & Functional Material of Gansu Province, College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of China
2.
Joint Laboratory of Atomic and Molecular Physics, Northwest Normal University and Institute of Modern Physics of Chinese Academy of Sciences, Lanzhou 730070, People's Republic of China

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Corresponding author:
Duixiong SUN, E-mail: sundx@nwnu.edu.cn

Chenzhong DONG, E-mail: dongcz@nwnu.edu.cn
Received Date: April 13, 2022
Revised Date: May 31, 2022
Accepted Date: June 05, 2022
Available Online: December 10, 2023
Published Date: July 05, 2022

Graphical Abstract

Abstract

Abstract

Laser-induced breakdown spectroscopy-assisted glow discharge (LIBS-GD) for analysis of elements in liquid was proposed, and it was applied to detect heavy metals in highly sensitive mixed solutions of Cu and Cr. During the experiments of GD and LIBS-GD, the experimental parameters have been optimized and the optimal voltage is 450 V, laser energy is 60 mJ, and the delay time is 4000 ns. Furthermore, the calibration curves of Cu and Cr under GD and LIBS-GD experiments have been established, and the limits of detection (LODs) of Cu and Cr were obtained with the method of GD and LIBS-GD, respectively. The LOD of Cu decreased from 3.37 (GD) to 0.16 mg l^-1 (LIBS-GD), and Cr decreased from 3.15 to 0.34 mg l^-1. The results prove that the capability of elemental detection under LIBS-GD has improved compared with the GD method. Therefore, LIBS-GD is expected to be developed into a highly sensitive method for sewage detection.
- laser-induced breakdown spectroscopy,
- glow discharge,
- heavy metal,
- limits of detection

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Acknowledgments

This work was supported by National Natural Science Foundation of China (Nos. 61965015, 11564037, and 161741513), the Industrial Support Program for Colleges of Gansu Province (No. 2020C-17), the Science and Technology Project of Gansu Province (No. 21JR7RA131), and the Young Teachers Scientific Research Ability Promotion Plan of Northwest Normal University (No. NWNU-LKQN2019-1).

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Improved sensitivity on detection of Cu and Cr in liquids using glow discharge technology assisted with LIBS

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