Improvement of β-phase crystal formation in a BaTiO<sub>3</sub>-modified PVDF membrane

Lin SHEN (申林); Lei GONG (宫蕾); Shuhua CHEN (陈淑花); Shiping ZHAN (詹世平); Cheng ZHANG (章程); Tao SHAO (邵涛)

doi:10.1088/2058-6272/aaada8

Plasma Science and Technology > 2018 > 20(6): 65510-065510. > DOI: 10.1088/2058-6272/aaada8

Lin SHEN (申林), Lei GONG (宫蕾), Shuhua CHEN (陈淑花), Shiping ZHAN (詹世平), Cheng ZHANG (章程), Tao SHAO (邵涛). Improvement of β-phase crystal formation in a BaTiO₃-modified PVDF membrane[J]. Plasma Science and Technology, 2018, 20(6): 65510-065510. DOI: 10.1088/2058-6272/aaada8

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Improvement of β-phase crystal formation in a BaTiO₃-modified PVDF membrane

¹ Department of Environment and Chemical Engineering, Dalian University, Dalian 116622, People’s Republic of China
² Liaoning Engineering Laboratory for Special Optical Functional Crystals, Dalian University, Dalian 116622, People’s Republic of China
³ Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China
⁴ University of Chinese Academy of Sciences, Beijing 100039, People’s Republic of China

Funds: The authors gratefully acknowledge the financial support from the Opening Project of the State Key Laboratory of Polymer Materials Engineering (Sichuan University)(Grant No. Sklpme2015-4-24) and the Provincial Department of Education Science General Foundation of Liaoning (Contract No. L2015017).

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Received Date: January 06, 2018

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Abstract

Abstract

In this paper, low temperature plasma is used to modify the surface of barium titanate (BaTiO₃) nanoparticles in order to enhance the interfacial compatibility between ferroelectric poly (vinylidene fluoride)(PVDF) and BaTiO₃ nanoparticles. The results demonstrate that oxygenic groups are successfully attached to the BaTiO₃ surface, and the quantity of the functional groups increases with the treatment voltage. Furthermore, the effect of modified BaTiO₃ nanoparticles on the morphology and crystal structure of the PVDF/BaTiO₃ membrane is investigated. The results reveal that the dispersion of BaTiO₃nanoparticles in the PVDF matrix was greatly improved due to the modification of the BaTiO₃ nanoparticles by air plasma. It is worth noting that the formation of a β-phase in a PVDF/modified BaTiO₃ membrane is observably promoted, which results from the strong interaction between PVDF chains and oxygenic groups fixed on the BaTiO₃ surface and the better dispersion of BaTiO₃ nanoparticles in the PVDF matrix. Besides, the PVDF/modified BaTiO₃ membrane at the treatment voltage of 24 kV exhibits a lower water contact angle (≈68.4°)compared with the unmodified one (≈86.7°). Meanwhile, the dielectric constant of PVDF/BaTiO₃ nanocomposites increases with the increase of working voltage.
- PVDF,
- BaTiO₃,
- nanocomposite,
- non-thermal plasma,
- β-phase,
- ferroelectric

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Improvement of β-phase crystal formation in a BaTiO₃-modified PVDF membrane

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