DBD coupled with MnOx/γ-Al<sub>2</sub>O<sub>3</sub> catalysts for the degradation of chlorobenzene

Yanghaichao LIU (刘杨海超); Liping LIAN (连莉萍); Weixuan ZHAO(赵玮璇); Renxi ZHANG (张仁熙); Huiqi HOU (侯惠奇)

doi:10.1088/2058-6272/ab69bc

Plasma Science and Technology > 2020 > 22(3): 34016-034016. > DOI: 10.1088/2058-6272/ab69bc

Yanghaichao LIU (刘杨海超), Liping LIAN (连莉萍), Weixuan ZHAO(赵玮璇), Renxi ZHANG (张仁熙), Huiqi HOU (侯惠奇). DBD coupled with MnOx/γ-Al₂O₃ catalysts for the degradation of chlorobenzene[J]. Plasma Science and Technology, 2020, 22(3): 34016-034016. DOI: 10.1088/2058-6272/ab69bc

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DBD coupled with MnOx/γ-Al₂O₃ catalysts for the degradation of chlorobenzene

¹ Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP³), Institute of Environmental Science, Fudan University, Shanghai 200433, People's Republic of China
² National Engineering Laboratory for VOCs Pollution Control Material & Technology, University of Chinese Academy of Sciences, Beijing 100049, People's Republic of China

Funds: The financial support for this research was provided by National Natural Science Foundation of China (No. 21577023), the Special Research Project on Causes and Control Technology of Air Pollution (Nos. 2017YFC0212905), and the Science and Technology Innovation Action Project Supported by the Science and Technology Commission of Shanghai Municipality (No. 18DZ1202605).

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Received Date: August 31, 2019
Revised Date: January 06, 2020
Accepted Date: January 08, 2020

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Abstract

Abstract

This paper investigates the degradation of chlorobenzene by dielectric barrier discharge (DBD) coupled with MnOx/γ-Al₂O₃ catalysts. MnOx/γ-Al₂O₃catalysts were prepared using the impregnation method and were characterized in detail by N₂ adsorption/desorption, x-ray diffraction and x-ray photoelectron spectroscopy. Compared with the single DBD reactor, the coupled reactor has a better performance on the removal rate of chlorobenzene, the selectivity of CO_x, and the inhibition of ozone production, especially at low discharge voltages. The degradation rate of chlorobenzene and selectivity of CO_x can reach 96.3% and 53.0%, respectively, at the specific energy density of 1350 J l^–1. Moreover, the ozone concentration produced by the discharge is significantly reduced because the MnOx/Al₂O₃ catalysts contribute to the decomposition of ozone to form oxygen atoms for the oxidation of chlorobenzene. In addition, based on analysis of the byproducts, the decomposition mechanism of chlorobenzene in the coupled reactor is also discussed.
- plasma catalytsis system,
- chlorinated VOCs,
- MnOx/Al₂O₃ catalysts

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References (57)

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DBD coupled with MnOx/γ-Al2O3 catalysts for the degradation of chlorobenzene

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DBD coupled with MnOx/γ-Al₂O₃ catalysts for the degradation of chlorobenzene