Plasma-catalytic degradation of tetracycline hydrochloride over Mn/γ-Al2O3 catalysts in a dielectric barrier discharge reactor

Baowei WANG (王保伟); Chao WANG (王超); Shumei YAO (姚淑美); Yeping PENG (彭叶平); Yan XU (徐艳)

doi:10.1088/2058-6272/ab079c

Plasma Science and Technology > 2019 > 21(6): 65503-065503. > DOI: 10.1088/2058-6272/ab079c

Baowei WANG (王保伟), Chao WANG (王超), Shumei YAO (姚淑美), Yeping PENG (彭叶平), Yan XU (徐艳). Plasma-catalytic degradation of tetracycline hydrochloride over Mn/γ-Al₂O₃ catalysts in a dielectric barrier discharge reactor[J]. Plasma Science and Technology, 2019, 21(6): 65503-065503. DOI: 10.1088/2058-6272/ab079c

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Plasma-catalytic degradation of tetracycline hydrochloride over Mn/γ-Al₂O₃ catalysts in a dielectric barrier discharge reactor

Key Laboratory for Green Chemical Technology of the Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China

Funds: This work is financially supported by National Key Research and Development Program of China (No. 2016YFB0600703) and Shijiazhuang City Important Science and Technology project (No. 176240857A).

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Received Date: November 13, 2018

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Abstract

Abstract

A coaxial dielectric barrier discharge (DBD) reactor was used for plasma-catalytic degradation of tetracycline hydrochloride over a series of Mn/γ-Al₂O₃ catalysts prepared by the incipient wetness impregnation method. The combination of plasma and the Mn/γ-Al₂O₃ catalysts significantly enhanced the degradation efficiency of tetracycline hydrochloride compared to the plasma process alone, with the 10% Mn/γ-Al₂O₃ catalyst exhibiting the best tetracycline hydrochloride degradation efficiency. A maximum degradation efficiency of 99.3% can be achieved after 5 min oxidation and a discharge power of 1.3 W, with only 69.7% by a single plasma process. The highest energy yield of the plasma-catalytic process is 91.7 gkWh⁻¹. Probable reaction mechanisms of the plasma-catalytic removal of tetracycline hydrochloride were also proposed.
- antibiotics,
- dielectric barrier discharge,
- Mn/γ-Al₂O₃,
- plasma-catalytic,
- tetracycline hydrochloride hydrochloride

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[1]	Carvalho I T and Santos L 2016 Environ. Int. 94 736
[2]	Zheng S L et al 2011 Chemosphere 84 1677
[3]	Xu J et al 2014 Sci. Total Environ. 497–498 267
[4]	Marti E et al 2014 Water Res. 61 67
[5]	Magureanu M, Mandache N B and Parvulescu V I 2015 Water Res. 81 124
[6]	Stratton G R et al 2015 Chem. Eng. J. 273 543
[7]	Hu P et al 2015 Ind. Eng. Chem. Res. 54 8277
[8]	Jiang B et al 2012 Chem. Eng. J. 204–206 32
[9]	Kim K S, Kam S K and Mok Y S 2015 Chem. Eng. J. 271 31
[10]	Vanraes P et al 2015 J. Hazard. Mater. 299 647
[11]	D?ugosz M et al 2015 J. Hazard. Mater. 298 146
[12]	Hijosa-Valsero M et al 2013 J. Hazard. Mater. 262 664
[13]	Jiang B et al 2014 Chem. Eng. J. 236 348
[14]	He D et al 2014 Chem. Eng. J. 258 18
[15]	Wang B W et al 2017 Chem. Eng. Sci. 168 90
[16]	Reddy P M K and Subrahmanyam C 2012 Ind. Eng. Chem. Res. 51 11097
[17]	Jin X L et al 2013 Ind. Eng. Chem. Res. 52 9726
[18]	Shen T D, Wang Q W and Tong S P 2017 Ind. Eng. Chem. Res. 56 10965
[19]	Malik M A 2010 Plasma Chem. Plasma Process. 30 21
[20]	Magureanu M et al 2011 Water Res. 45 3407
[21]	Zhang G Y et al 2017 J. Hazard. Mater. 323 719
[22]	Rosal R et al 2010 J. Hazard. Mater. 183 271
[23]	Nawrocki J and Kasprzyk-Hordern B 2010 Appl. Catal. B 99 27
[24]	Wang L et al 2016 J. Phys. Chem. C 120 6136
[25]	Wang B W et al 2017 Chem. Eng. J. 322 679
[26]	Vázquez A, Hernández-Uresti D B and Obregón S 2016 Appl. Surf. Sci. 386 412
[27]	Xue J J et al 2015 ACS Appl. Mater. Interfaces 7 9630
[28]	Hernández-Uresti D B et al 2016 J. Photochem. Photobiol. A 324 47
[29]	Zhu X B et al 2016 Chemosphere 155 9
[30]	Lu M J et al 2015 Catal. Today 242 274
[31]	Tepluchin M et al 2014 Chem. Cat. Chem. 6 1763
[32]	Li Y P et al 2015 Appl. Surf. Sci. 324 736
[33]	Zhu X B et al 2015 Catal. Today 256 108
[34]	Huang R H et al 2012 Chem. Eng. J. 180 19
[35]	Huang R H et al 2011 Appl. Catal. B 106 264
[36]	Li S Y et al 2017 J. Colloid Interface Sci. 504 238
[37]	Li C H et al 2017 Chem. Eng. J. 325 624
[38]	Dong Y M et al 2007 Catal. Commun. 8 1599
[39]	He K et al 2008 J. Hazard. Mater. 159 587
[40]	Mok Y S, Jo J O and Whitehead J C 2008 Chem. Eng. J. 142 56
[41]	Sun Q Q et al 2015 J. Hazard. Mater. 286 276
[42]	Maroga Mboula V et al 2012 J. Hazard. Mater. 209–210 355
[43]	Li J H et al 2016 Appl. Catal. A 524 105
[44]	Khan M H, Bae H and Jung J Y 2010 J. Hazard. Mater. 181 659
[45]	Wan Y et al 2013 Chemosphere 90 1427

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2.	Eremin, D., Kemaneci, E., Matsukuma, M. et al. Modeling of very high frequency large-electrode capacitively coupled plasmas with a fully electromagnetic particle-in-cell code. Plasma Sources Science and Technology, 2023, 32(4): 044007. DOI:10.1088/1361-6595/accecb
3.	Sun, G., Zhang, S., Sun, A. et al. On the electron sheath theory and its applications in plasma-surface interactions. Plasma Science and Technology, 2022, 24(9): 095401. DOI:10.1088/2058-6272/ac6aa7
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5.	Vass, M., Wilczek, S., Derzsi, A. et al. Evolution of the bulk electric field in capacitively coupled argon plasmas at intermediate pressures. Plasma Sources Science and Technology, 2022, 31(4): 045017. DOI:10.1088/1361-6595/ac6361
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Plasma-catalytic degradation of tetracycline hydrochloride over Mn/γ-Al₂O₃ catalysts in a dielectric barrier discharge reactor