Analysis of metallic elements dissolution in the Astragalus at different decocting time by using LIBS technique

Weiwei HAN (韩伟伟); Maogen SU (苏茂根); Duixiong SUN (孙对兄); Yaopeng YIN (殷耀鹏); Yupeng WANG (王玉鹏); Chunli GAO (高春丽); Fuchun YANG (杨富春); Yanbiao FU (符彦飙)

doi:10.1088/2058-6272/ab861b

Plasma Science and Technology > 2020 > 22(8): 85501-085501. > DOI: 10.1088/2058-6272/ab861b

Weiwei HAN (韩伟伟), Maogen SU (苏茂根), Duixiong SUN (孙对兄), Yaopeng YIN (殷耀鹏), Yupeng WANG (王玉鹏), Chunli GAO (高春丽), Fuchun YANG (杨富春), Yanbiao FU (符彦飙). Analysis of metallic elements dissolution in the Astragalus at different decocting time by using LIBS technique[J]. Plasma Science and Technology, 2020, 22(8): 85501-085501. DOI: 10.1088/2058-6272/ab861b

Citation:

PDF (1353 KB)

Analysis of metallic elements dissolution in the Astragalus at different decocting time by using LIBS technique

¹ Key Laboratory of Atomic and Molecular Physics & Functional Material of Gansu Province, College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of China
² National Ancient Wall Painting and Earthen Archaeological Site Engineering Research Centre, Dunhuang 736200, People's Republic of China

Funds: This work was supported by National Natural Science Foundation of China (Nos. 61965015, 11564037, 61741513, 11364037), The Special Fund Project for Guiding Scientific and Technological Innovation of Gansu Province (No. 2019zx-10), Young Teachers Scientific Research Ability Promotion Plan of Northwest Normal University (No. NWNU-LKQN2019-1).

More Information

Received Date: February 04, 2020
Revised Date: March 31, 2020
Accepted Date: April 01, 2020

Graphical Abstract

Abstract

Abstract

Astragalus is an important traditional Chinese herb that has therapeutic potential in the treatment of diseases. In this study, the dissolution of metallic elements during the material decoction process was investigated using laser-induced breakdown spectroscopy (LIBS). The Ca, Mg, Al, and Fe in the drug residues, liquid, and vapor were selected for the study of the transfer of elements after different decocting times. It was found that the intensities of the spectral lines for these elements in the drug liquid increased with increasing decocting times. The contrast trend was observed in the residues and only calcium was detected in the vapor. Furthermore, the relative mass concentrations of Ca, Mg, Al, and Fe in the liquid were quantitatively determined by a combination of the standard addition method and calibration-free-LIBS method by adding the standard concentration solution of Cu and Cd elements into the drug liquids, it can be found that the maximum error between Cd concentration calculated by internal CF-LIBS and the standard is within 10%. This provides a new method of achieving the on-line monitoring and analysis of metallic elements in the production of traditional Chinese medicines.

FullText(HTML)

References (32)

References

[1]	Brand E et al 2017 J. Ethnopharmacol. 200 209
[2]	Cicchella D et al 2010 J. Geochem. Explor. 107 336
[3]	Yang M H, Chen J M and Zhang X H 2005 Chromatographia 62 499
[4]	Liu C X et al 2017 Chin. Herb. Med. 9 3
[5]	Chan K 2005 J. Ethnopharmacol. 96 1
[6]	Nogami M et al 1986 Chem. Pharm. Bull. 34 3854
[7]	Li S and Zhang B 2013 Chin. J. Nat. Med. 11 110
[8]	Kao C M et al 1993 J. Chin. Chem. Soc. 40 33
[9]	Li X D et al 1995 Chem. Geol. 124 109
[10]	Eggins S M, Kinsley L P J and Shelley J M G 1998 Appl. Surf.Sci. 127–129 278
[11]	Liu Y S et al 2008 Chem. Geol. 257 34
[12]	Ko K M and Ng K M Asia Pacific Biotech News 8 1338
[13]	Hohreiter V et al 2005 Anal. Chem. 77 1118
[14]	Lin Q Y et al 2017 Appl. Opt. 56 5092
[15]	Bulatov V, Krasniker R and Schechter I 1998 Anal. Chem.70 5302
[16]	Gudmundsson S H et al 2019 Spectrochim. Acta B 158 105646
[17]	Winefordner J D et al 2004 J. Anal. At. Spectrom. 19 1061
[18]	Wang J M et al 2018 Anal. Lett. 51 575
[19]	Myakalwar A K et al 2011 Talanta 87 53
[20]	Tiwari P K et al 2018 Lasers Med. Sci. 33 263
[21]	St-Onge L et al 2002 Spectrochim. Acta B 57 1131
[22]	Cahoon E M and Almirall J R 2012 Anal. Chem. 84 2239
[23]	Wang Y Q et al 2018 Microchem. J. 137 318
[24]	Cho W C S and Leung K N 2007 Cancer Lett. 252 43
[25]	Shao B M et al 2004 Biochem. Biophys. Res. Commun.320 1103
[26]	Zhang M L et al 2009 J. Integr. Plant Biol. 51 889
[27]	Wu C et al 2019 J. Anal. At. Spectrom. 34 1478
[28]	Sun D X et al 2018 Anal. Methods 10 2595
[29]	Yin Y P et al 2019 Opt. Laser Technol. 120 105689
[30]	Wen G H et al 2014 Plasma Sci. Technol. 16 598
[31]	Cao S Q et al 2018 Phys. Plasmas 25 023304
[32]	Ciucci A et al 1999 Appl. Spectrosc. 53 960

[1]	Changle LIU, Lei LI, Yanzi HE, Peng ZHANG, Yu ZHOU, Jun SONG, Songtao WU. An innovative approach to effective breeding blanket design for future fusion reactors[J]. Plasma Science and Technology, 2024, 26(10): 105601. DOI: 10.1088/2058-6272/ad5a66
[2]	Zhongtian WANG (王中天), Huidong LI (李会东), Xueke WU (吴雪科). Loss-cone instabilities for compact fusion reactor and field-reversed configuration[J]. Plasma Science and Technology, 2019, 21(2): 25101-025101. DOI: 10.1088/2058-6272/aaead9
[3]	Dongye ZHAO (赵栋烨), Cong LI (李聪), Yong WANG (王勇), Zhiwei WANG (王志伟), Liang GAO (高亮), Zhenhua HU (胡振华), Jing WU (吴婧), Guang-Nan LUO (罗广南), Hongbin DING (丁洪斌). Temporal and spatial dynamics of optical emission from laser ablation of the first wall materials of fusion device[J]. Plasma Science and Technology, 2018, 20(1): 14022-014022. DOI: 10.1088/2058-6272/aa96a0
[4]	Shanwen ZHANG (张善文), Yuntao SONG (宋云涛), Linlin TANG (汤淋淋), Zhongwei WANG (王忠伟), Xiang JI (戢翔), Shuangsong DU (杜双松). Electromagnetic–thermal–structural coupling analysis of the ITER edge localized mode coil with fiexible supports[J]. Plasma Science and Technology, 2017, 19(5): 55601-055601. DOI: 10.1088/2058-6272/aa57f4
[5]	Hantian ZHANG (张含天), Tianwei LI (厉天威), Bing LUO (罗兵), Yi WU (吴翊), Fei YANG (杨飞), Hao SUN (孙昊), Li TANG (唐力). Influence of the gassing materials on the dielectric properties of air[J]. Plasma Science and Technology, 2017, 19(5): 55504-055504. DOI: 10.1088/2058-6272/aa57f5
[6]	ZHANG Xiujie (张秀杰), PAN Chuanjie (潘传杰), XU Zengyu (许增裕). MHD Stability Analysis and Flow Controls of Liquid Metal Free Surface Film Flows as Fusion Reactor PFCs[J]. Plasma Science and Technology, 2016, 18(12): 1204-1214. DOI: 10.1088/1009-0630/18/12/11
[7]	WANG Shijia (王时佳), WANG Shaojie (王少杰). Effect of Fuelling Depth on the Fusion Performance and Particle Confinement of a Fusion Reactor[J]. Plasma Science and Technology, 2016, 18(12): 1155-1161. DOI: 10.1088/1009-0630/18/12/03
[8]	YANG Yu (杨愚), S. MARUYAMA, A. FOSSEN, F. VILLERS, G. KISS, ZHANG Bo (张博), LI Bo (李波), JIANG Tao (江涛), HUANG Xiangmei (黄向玫). Nuclear Safety Functions of ITER Gas Injection System Instrumentation and Control and the Concept Design[J]. Plasma Science and Technology, 2016, 18(8): 875-878. DOI: 10.1088/1009-0630/18/8/15
[9]	ZHAO Dongye(赵栋烨), FARID Nazar(纳扎), HAI Ran(海然), WU Ding(吴鼎), DING Hongbin(丁洪斌). Diagnostics of First Wall Materials in a Magnetically Confined Fusion Device by Polarization-Resolved Laser-Induced Breakdown Spectroscopy[J]. Plasma Science and Technology, 2014, 16(2): 149-154. DOI: 10.1088/1009-0630/16/2/11
[10]	HAO Junchuan (郝俊川), SONG Yuntao (宋云涛), WANG Xiaoyu (王晓宇), K. IOKI, DU Shuangsong (杜双松), JI Xiang (戢翔), FENG Changle (冯昌乐), XU Yang (徐扬). Static Structural Analysis for a Neutron Shielding Block in ITER[J]. Plasma Science and Technology, 2013, 15(2): 142-147. DOI: 10.1088/1009-0630/15/2/13