Plasma-assisted Ru/Zr-MOF catalyst for hydrogenation of CO<sub>2</sub> to methane

Weiwei XU (徐卫卫); Xiuling ZHANG (张秀玲); Mengyue DONG (董梦悦); Jing ZHAO (赵静); Lanbo DI (底兰波)

doi:10.1088/2058-6272/aaf9d2

Plasma Science and Technology > 2019 > 21(4): 44004-044004. > DOI: 10.1088/2058-6272/aaf9d2

Weiwei XU (徐卫卫), Xiuling ZHANG (张秀玲), Mengyue DONG (董梦悦), Jing ZHAO (赵静), Lanbo DI (底兰波). Plasma-assisted Ru/Zr-MOF catalyst for hydrogenation of CO₂ to methane[J]. Plasma Science and Technology, 2019, 21(4): 44004-044004. DOI: 10.1088/2058-6272/aaf9d2

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Plasma-assisted Ru/Zr-MOF catalyst for hydrogenation of CO₂ to methane

College of Physical Science and Technology, Dalian University, Dalian 116622, People’ s Republic of China

Funds: This work is supported by National Natural Science Foundation of China (Nos. 21673026, 21773020, 11505019), the Liaoning Innovative Talents in University (No. LR2017025), and the Liaoning Natural Science Foundation (No. 20180550085).

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Received Date: October 09, 2018

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Abstract

As an important type of metal–organic framework (MOF), Zr-MOF shows excellent CO₂ adsorption performance. In this work, a Zr-MOF was synthesized by a solvothermal method and adopted to support Ru through simple incipient-wetness impregnation. Then the Ru/Zr-MOF was applied for CO₂ hydrogenation (V_H2: V_CO2= 4:1) with the assistance of dielectric barrier discharge (DBD) plasma. The hydrogenation of CO₂results showed that methane was produced selectively under the synergistic effect between plasma and the Ru/Zr-MOF catalyst, and the selectivity and yield of methane reached 94.6% and 39.1%, respectively. The XRD and SEM analyses indicate that the basic crystalline phase structure and morphology of the Zr-MOF and Ru/Zr-MOF remained the same after DBD plasma treatment, suggesting that the catalysts are stable in plasma. The guest molecules in the pores of the Zr-MOF are removed and the Ru³⁺ ions are reduced to metallic Ru⁰ in the reduction atmosphere according to the BET and XPS results, which are responsible for the high performance of plasma with the Ru/Zr-MOF catalyst. In situ optical emission spectra of pure plasma, plasma with Zr-MOF, and plasma with Ru/Zr-MOF were measured, and the active species of C, H and CH for CO₂hydrogenation were detected. The plasma-assisted Ru/Zr-MOF exhibited high catalytic activity and stability in CO₂ hydrogenation to methane, and it has great guiding significance for CO₂ hydrogenation by using plasma and MOF materials.
- dielectric barrier discharge,
- cold plasma,
- Zr-MOF,
- carbon dioxide hydrogenation, methane

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Plasma-assisted Ru/Zr-MOF catalyst for hydrogenation of CO₂ to methane