Effect of Cr₂O₃ nanosheet insertion on the deuterium permeation behavior of a Cr-Zr-O coating

In this study, a Cr₂O₃ nanosheet (Cr₂O₃ NS) inserted Cr-Zr-O coating was developed as a hydrogen isotope permeation barrier. The Cr₂O₃ NSs, fabricated by rapid heat treatment, were amorphous with a thickness of only several nanometers. These Cr₂O₃ NSs were then incorporated into a Cr-Zr-O multi-metal oxide composite coating via a dip-coating method to form a coating. The effect of the Cr₂O₃ NS concentration on the morphology, microstructure and deuterium permeation resistance of the coating was studied. With the addition of 1.0 g l^-1 Cr₂O₃ NSs, compared with the Cr-Zr-O coating without NSs, the permeation reduction factor of the resultant coating was enhanced from 249 ℃ to 575 ℃ at 500 ℃. The coating, with a thickness of nearly 193 nm, achieved a comparable deuterium resistance that was above two orders of magnitude higher than the steel substrate. The results show that ceramic NSs can serve as effective fillers for enhancing the coating performance when functioning as a hydrogen isotope barrier.