Simultaneous Determination of Trace Lead and Chromium in Water Using Laser-Induced Breakdown Spectroscopy and Paper Substrate

YU Youli(於有利); ZHOU Weidong(周卫东); QIAN Huiguo(钱慧国); SU Xuejiao(苏雪娇); REN Ke(任可)

doi:10.1088/1009-0630/16/7/09

Plasma Science and Technology > 2014 > 16(7): 683-687. > DOI: 10.1088/1009-0630/16/7/09

YU Youli(於有利), ZHOU Weidong(周卫东), QIAN Huiguo(钱慧国), SU Xuejiao(苏雪娇), REN Ke(任可). Simultaneous Determination of Trace Lead and Chromium in Water Using Laser-Induced Breakdown Spectroscopy and Paper Substrate[J]. Plasma Science and Technology, 2014, 16(7): 683-687. DOI: 10.1088/1009-0630/16/7/09

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Simultaneous Determination of Trace Lead and Chromium in Water Using Laser-Induced Breakdown Spectroscopy and Paper Substrate

1 Institute of Information Optics, Zhejiang Normal University, Jinhua 21004, China 2 Physics Department, University of Science and Technology of China, Hefei 230026, China

Funds: supported by National Natural Science Foundation of China (No. 61178034), Key Research Project of University of Zhejiang Province, China (No. ZD2009006) and the Program for Innovative Research Team, Zhejiang Normal University, China

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Received Date: May 02, 2013

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Abstract

Abstract

Toxic metals such as lead and chromium in aqueous solutions have been analyzed simultaneously by laser-induced breakdown spectroscopy (LIBS), in which the ordinary printing paper is used as a liquid absorber which was immerged into Pb(NO 3 ) 2 and Cr(NO 3 ) 3 aqueous solution to enrich the heavy metals. This method overcomes the drawbacks of splashing and low sensitivity in ordinary LIBS analysis of water, in which a laser beam is directly focused on a liquid surface. A good signal intensity and reproducibility has been demonstrated. The Pb 405.78 nm and Cr 427.48 nm spectral lines are used as the analytical lines. The variation of line intensity with immersion time was investigated. The calibration curve for quantitative measurement of Pb and Cr in water was established, and the detection limits are 0.033 mg/L and 0.026 mg/L respectively, which is about 2-3 orders of magnitude better than that in the ordinary LIBS analysis of heavy metal in solution.
- LIBS,
- solution,
- quantitative analysis,
- paper substrate

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References (20)

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