
Citation: | Zhen SONG, Junxiao WANG, Gang WANG, Lei ZHANG, Shuqing WANG, Wanfei ZHANG, Xiaofei MA, Zhenrong LIU, Xuebin LUO, Weiguang MA, Zefu YE, Zhujun ZHU, Wangbao YIN, Suotang JIA. A theoretical study of the signal enhancement mechanism of coaxial DP-LIBS[J]. Plasma Science and Technology, 2024, 26(5): 055508. DOI: 10.1088/2058-6272/ad1ed1 |
In the field of dual-pulse laser-induced breakdown spectroscopy (DP-LIBS) research, the pursuit of methods for determining pulse intervals and other parameters quickly and conveniently in order to achieve optimal spectral signal enhancement is paramount. To aid researchers in identification of optimal signal enhancement conditions and more accurate interpretation of the underlying signal enhancement mechanisms, theoretical simulations of the spatiotemporal processes of coaxial DP-LIBS-induced plasma have been established in this work. Using a model based on laser ablation and two-dimensional axisymmetric fluid dynamics, plasma evolutions during aluminum–magnesium alloy laser ablation under single-pulse and coaxial dual-pulse excitations have been simulated. The influences of factors, such as delay time, laser fluence, plasma temperature, and particle number density, on the DP-LIBS spectral signals are investigated. Under pulse intervals ranging from 50 to 1500 ns, the time evolutions of spectral line intensity, dual-pulse emission enhancement relative to the single-pulse results, laser irradiance, spatial distribution of plasma temperature and species number density, as well as laser irradiance shielded by plasma have been obtained. The study indicates that the main reason behind the radiation signal enhancement in coaxial DP-LIBS-induced plasma is attributed to the increased species number density and plasma temperature caused by the second laser, and it is inferred that the shielding effect of the plasma mainly occurs in the boundary layer of the stagnation point flow over the target surface. This research provides a theoretical basis for experimental research, parameter optimization, and signal enhancement tracing in DP-LIBS.
Low temperature plasma is a kind of mixture with electrons, ions and neutral particles, generated by suppling enough energy from constant electric field (DC), alternating electric field (AC), radio frequency (RF) or microwave power (MW) [1]. The non-equilibrium nature of the huge difference in electron temperature and gas temperature, leads to utilization with low temperature plasma in area of coating [2], etching [3], medicine [4] and gas conversion [5], etc. Recently, microwave discharge plasma is considered as an outstanding plasma source for application and fundamental research with unique characters of electrodeless discharge, flexible controlling, wide range of operating pressure and discharge volume. Many types of microwave discharge devices are designed for scientific and industrial research which can be classified with working pressure, frequency and microwave coupling methods [6].
The surface wave plasma is sustained by means of electromagnetic wave propagating along the interface between plasma-dielectric media [7–11], in case the electron density is higher than the critical value which depends on the frequency of electromagnetic field (7.46×1016 m-3 for 2.45 GHz). The traditional surface wave discharge based on the quartz tube and waveguide, generates plasma inside the tube for gas conversion, plasma chemistry and modeling research, such as 'Surfatron' and 'Surfaguide' [12–14]. In order to meet the industrial requirements, the surface wave linear plasma called 'Duo-plasmaline' [15, 16] has been designed with plasma extending linearly uniform, which has great potential to achieve large area plasma source by parallel arrangement. The basic principle of surface wave linear plasma is supplying microwave power simultaneously from two ends of coaxial waveguide which consists of a copper rod and a quartz tube in the vacuum chamber. Microwave power penetrates into the vacuum chamber through the quartz tube to excite working gas under low pressure, generating linear plasma along the surface of quartz tube. Plasma with density higher than the critical number plays a role of outer conductor, meanwhile the copper rod comes as an inner conductor, which leads the electromagnetic wave propagating between the interface of plasma and quartz tuberealizing surface wave discharge. The mechanism of supplying dual microwave powers and the structure of coaxial waveguide decrease the attenuation of electromagnetic wave, achieving to a high degree of axial homogeneity and stability. At present, the application experiments and numerical simulation works on the surface wave linear plasma have made great progresses. In 1997s, Petasch et al [16] first developed the linearly extended plasma source excited by the dual 2.45 GHz microwave powers at a pressure of 10 mbar. The Langmuir probe was used to measure the electron density and temperature to find the excellent axial homogeneity. Then, numerous application research on material deposition and treatment through this kind of plasma source was produced. In the work of Takatoshi Yamada et al [17], a 2D roll-to-roll microwave plasma CVD device by several linear surface wave plasma sources for fabrication of large area graphene films was developed, realizing the controlling of film qualities by adjusting gas mixture ratio and pressure. Kromka et al [18] achieved the growth of the diamond thin films over large area (up to 20×10 cm2) by linear antenna microwave plasma CVD process from a CH4/H2 gas mixture under pressure of 0.1 mbar and 2 mbar. Liehr et al [19] used two tapered metal shields located inside the two ends of quartz tube to improve the uniformity of coaxial line plasma source, and then a variety of thin films were deposited. Apart from experiments, numerical simulation is recognized as a good approach dedicated to find inner physical process of plasma source. Jicheng Zhou et al [20] built a numerical model of linear plasma with length of 1550 mm based on COMSOL software, coupling different physical field to analyze the effect of the microwave power, gas pressure and magnetic flux density. Rahimi et al [21] presented a two-dimensional (2D) plasma model through Plasimo platform based on the plasma fluid theory with the pressure in the range of 2–8 mbar. After comparing with experimental results, the good agreement on electron density and temperature was found.
In this work, the coaxial surface wave linear plasma source ignited by 2.45 GHz microwave powers with length over 600 mm under low pressure is developed, which is an extending for previous numerical simulation research [22–24]. Argon plasma parameters under different discharge conditions are measured by optical emission spectroscopy, which is confirmed as a credible plasma diagnostic technology by many researchers [25–28]. In section 2, the experimental device and measurement system are presented. The spectral data are collected along axial direction steady and successfully with the help of slide block and track. In section 3, the analyses of electron excitation temperature, molecule rotational temperature and electron density based on spectrum are described, including the results of axial uniformity analysis. Finally, a brief summary is given in section 4. Such results may provide a better understanding of experimental phenomena in the surface wave linear plasma, and help for figuring out the parameters of our device.
The schematic diagram of experimental device is shown in figure 1(a). The reaction chamber has the upper discharge region and the lower diffusion region where a substrate table for material treatment is sited. Working gas is input through two tubes with apertures sited inside the top of chamber and the vacuum system connected from the bottom. One vacuum gauge is installed with the diffusion region of chamber to record the pressure. The dominant coaxial waveguide could be considered as two parts: (1) the first part is located inside the discharge chamber, consisting of a copper rod (Φ=8 mm) and a quartz tube (Φ=26 mm) with length of 600 mm; (2) the second part is located outside of chamber in the two ends, connecting with designed specific microwave converter (TE10 to TEM), in which the quartz tube is replaced by copper tube (Φ=26 mm). The chamber is filled with argon gas under low pressure, and the gas inside the quartz tube is atmospheric air. Flowing air from the rubber tube on the plunger realizes cooling of copper rod. The electromagnetic waves from one microwave generator with frequency of 2.45 GHz are equally divided into two same microwave powers through the standard microwave power splitter connecting with the device by coaxial transport line. The standard microwave coaxial line converters of 2.45 GHz are used in our system for transition from rectangular waveguide of TE10 mode to coaxial line of TEM mode. Between the microwave power splitter and microwave generator, the waveguide with three tuners is adopted to adjust the wave reflection. In order to collect the optical signals emitted from plasma, the observing window of quartz plate is designed in the axial direction of discharge chamber with length of 550 mm and width of 50 mm. The position of observing window is pointed directly at quartz tube and the copper grid is introduced between the chamber and quartz plate to avoid microwave leaking.
The basic process of plasma discharge in the experimental device is as follows: electromagnetic waves are generated from 2.45 GHz microwave generator system, and divided equally into two microwave powers input by the microwave power splitter; microwave powers are launched from two ends of coaxial waveguide simultaneously and emit into the chamber through quartz tube to excite working gas producing plasma along the surface of quartz tube. The high-density plasma forms a self-consistent coaxial transmission line with the inner copper rod to keep electromagnetic wave propagating and plasma extending. In figure 2(b), the coaxial surface wave linear plasma device and discharge phenomena are shown, in which the linear plasma shape is observed obviously.
The crucial components of optical measurement system are lifting platform, axial sliding track, sliding block and optical emission spectrometer, as shown in figure 2. The experimental diagnosis picture is placed in the right corner. The optical detector is fixed on the sliding block cooperating with the sliding track to realize smoothly moving in the axial direction. The position of detector could be adjusted by the lifting platform where the optical plate and sliding track are mounted. The distance between detector and quartz observe window is smaller than 5 mm which can be adjusted. The detector is connected with spectrometer by the optical fiber, delivering spectrum data to the computer in time. The spectrometer used is the Multi-Channel Spectrometers (200–1000 nm) from AvaSpec Starline family including eight channels with observed wavelength step of 100 nm for each one. The resolution of each channel is averaged to 0.09 nm which is enough to record the lines information for analysis in our work.
For investigating the axial uniformity of the plasma, in every discharge, ten positions marked from a to j are chosen to measure along the axial direction. The detector moves from right side of the observing window using the sliding block and stops around 5 s in every position for the spectrum recording. The schematic graph of measurement positions can be found in the figure 3.
Because of the surface wave discharge mechanism, strong stand wave mode [29] appears when the pressure over 50 Pa in our device. Giving the consideration to film deposition in the future, the measurement experiments in this paper are chosen with lower pressure to carry out for analysis of uniformity and plasma situation. The microwave in all experiments is continuous wave mode instead of pulse. The experiments with single microwave power input from right side are also performed in comparable. The operational parameters are presented in the table 1 as bellow.
Parameters | Information and values |
Frequency and mode | 2.45 GHz with continuous wave mode |
Powers | Dual: 300 W/300 W, 400 W/400 W, 500 W/500 W |
Single: 600 W | |
Reflection | < 0.1% |
Pressure | 30 Pa, 50 Pa |
Basic pressure | 0.0133 Pa |
Gas | Argon (99.9%) |
Collecting suitable spectrum line to deliver the information we are looking for is significant in diagnosis of optical emission spectroscopy. Figure 4 shows the full spectrum from 250 to 900 nm under four typical experimental conditions, in which the spectral lines we want are observed. This full spectrum is the concatenation of seven segments from channel 1 to 7 (200–900 nm) with the same exposure time. First of all, the lines information of Ar atoms with high quality and resolution is shown. Then, the spectra of OH (
In the steady plasma discharge, the populations of particles in the upper and lower excited state obey the Boltzmann distribution in most cases. The electron excitation temperature is associated with electron energy and velocity, which can be obtained using Boltzmann plot method popularly [30, 31] without a standard source for calibration. The basic point of Boltzmann plot method is the intensity of different emission lines from different excited states of same atom (argon atom in this work) and the equation (1) is the expression for using [27, 32].
In(IkλkgkAki)=-1kBTexcEk+C. | (1) |
Here,
The typical Boltzmann plots are illustrated in the figures 5(a) and (b) under different types of microwave power input, and the spectrum data are both collected under pressure of 30 Pa at the position a. The linear fitting is fine enough with the correlation coefficient (r2) achieving to 0.95, which is reliable to obtain the electron excitation temperature under different experiments. The distributions of electron excitation temperature as a function of microwave power and pressure are shown in figures 6(a)–(c). The x axis starting from 50 mm represents for the distance from the right end position of the discharge chamber, which is described clearly in figure 3.
In figure 6(a), comparing with the results from dual microwave powers input, the excitation temperature decreased slight along the axial direction with only single microwave power launched. The feature of axial extending linear is found in the figures 6(b) and (c). The excitation temperature has improved a little with microwave power rising, because more energy is imported. Mostly, the effects on electron excitation temperature are collision frequency of electrons-neutral particles and energy absorbed per electron, which are associated with gas pressure [34]. Besides, the results of electron excitation temperature obtained from optical emission spectrum are averaged value, which may be declined when the input energy is shared by large number of particles. Due to the reasons mentioned above, the electron excitation temperature will be decreased with increasing gas pressure which is presented in figure 6(c). However, according to the results in figure 6, the influence coming from microwave power and pressure is very slight on electron excitation temperature, and all of them are almost around 1.0±0.1 eV keeping consistency with the works from Hübner et al in [35]. In the chapter 9 of the reference, a linear coaxial microwave is operated with argon plasma around 1 mbar and measured by Langmuir probe. The electron temperature is always about 0.8–1.5 eV with the pressure from 0.25 to 2 mbar.
In most cases of the non-equilibrium plasmas, the lifetime of ground state is significantly longer than the characteristic time for collisions, which lead the rotational temperature of the ground state as usually a good representation of the gas temperature with enough time to achieve the rotational distribution thermalized [36]. Due to the gas pressure in this work, the low-pressure limits collisions to occur during the lifetime of ground state whereby the electron excitation is the dominant excitation mechanism. In that case, the rotational distribution of the excite states is a mapping of the ground state, because the electron collision from the ground state is without change of rotational quantum numbers [37, 38]. Therefore, using rotational spectra of diatomic molecules (mostly diatomic) under excited states as a probe for gas temperature has made great success for many years, such as OH, NO [39] and N2 [40]. Herein, we especially note [36], in which the gas temperature from rotational lines was reviewed clearly, and the work from Gans [41] under the similar gas pressure range also proved that the method above could be adopted in this work.
The diatomic OH (
Figure 8 presents a comparison of the experimental emission data (the black circle dots) with the simulated profile (red line), which shows good agreement, especially at the position of peak in the head band (306–307 nm) and the tail band in 309 nm. The experimental conditions are at pressure of 30 Pa with single microwave power input (figure 8(a)) and dual microwave power input (figure 8(b)). Spectra in figure 8 are both obtained in the position iat the left side shown in figure 3. Therefore, the rotational temperature of OH radicals is lower with only single microwave power input from right side, corresponding to the weak intensity of head band in figure 8(a), comparing with dual microwave powers input case in figure 8(b). The values of temperature around 2000 K are found in our experiments, however the metal wall of outer plasma chamber is not much hotter than room temperature. That might be caused by the low thermal conductivity of the gas and large surface of chamber.
The distributions of OH rotational temperature under various experiments conditions are also analyzed in the figure 9. The trend of temperature appears generally axial downward from the single microwave power input side as shown in figure 9(a), and the axial uniformity of the rotational temperature is restored after launching two microwave powers simultaneously. From the figure 9(b), the gas is heated slightly by dozens of Kelvins with microwave power increasing, meanwhile the distribution shows more uniform under the higher microwave power. It is known that, the collision frequency between electrons and neutral particles increased by gas pressure will cause the promotion on temperature of ground state particles, like the microwave jet in atmospheric [31]. However, in the results of figure 9(c), with the gas pressure rising, the rotational temperature seems to have no change in the axial direction with the consideration of error of measurement, that might be because electron excitation dominates mechanism in surface wave plasma under low pressure (~50 Pa) instead of collided excitation. The weak collision is also the crucial reason for surface wave linear plasma to keep uniform in the long distance.
Electron density is a basic parameter to evaluate the situation of plasma source, whose distribution has significant effect on the quality and uniformity of the surface wave linear plasma in this work. Thus, the general fluctuation trend of plasma density is the focal point to pay attention to instead of exact value.
In our experiments, the profile of the Balmer line Hβ (486.1 nm) with broadening is observed in the spectra collected by optical emission spectrometer. The Stark broadening hydrogen Balmer series are typically applied for plasma diagnosis to determine the electron density, as Stark effect in the line shape is almost linear with the density of charged particles surrounding the emitter [44–46]. The full-widths at half-maximum (FWHM) of Stark broadening of the Hβ line can be used to calculate the electron density through expression as follows without considering either temperature or the perturbed masses [45]:
FWHM=4.8nm×(ne1023m-3)0.68116(nm). | (2) |
Actually, the experimental line shapes are the results of several plasma broadening mechanisms which are described in details in [47, 48]. Therefore, the Stark broadening profile has to be isolated and retrieved. The line profile of Hβ line could be fitted with the Voigt function with a value of FWHM, which can be represented in the convolution of the Gaussian shape and Lorentzian shape [25]:
∆λVoigt≈√(∆λLorentz2)2+(∆λGauss)2+∆λLorentz2(nm). | (3) |
Here, the
∆λGauss=√(∆λDoppler)2+(∆λInstrument)2(nm) | (4) |
wherein, the Doppler broadening
∆λDoppler=7.162×10-7×λ0√TgM(nm) | (5) |
Whereas the shape of Lorentzian profile is the sum of Stark broadening (
∆λLorentz=∆λStark+∆λvanderwaals+∆λresonance+∆λnatural(nm). | (6) |
In our case, the concentration of hydrogen is much smaller than argon gas, so the resonance broadening (
∆λvanderwaals=ConstantTg0.7(nm). | (7) |
The constant value depends on different lines and gas, which is 5.24 in our experiments. That coefficient is introduced from the table in [49], based on argon gas discharge and Hβ line used to diagnose.
Therefore, in order to receive the Stark broadening (
Figure 10 shows the recorded Hβ line in position a fitted with Voigt function, and the experimental conditions are (a) single microwave power input and (b) dual microwave powers input at pressure of 30 Pa. The types of microwave power input seem to have no obvious influence on the broadening recorded in the position near microwave power source. Because of the lower pressure, the broadening of line profile is not very large but enough to obtain the electron density and analysis the axial distribution in the range of error. The profiles also appear to have slight asymmetric and shift, which might be caused by the strong difference in the motion of electron and ions under the low pressure [50, 51]. However, the Voigt fitting in our process is nice enough with the coefficient of determination (R2) achieving into 0.98. Using the methods demonstrated before, the distributions of electron density along the axial direction under different experiment conditions are displayed in figure 11.
In figure 11(a), the trend of electron density declines along axial direction with only one microwave power supplied, and reveals uniform apparently after replacing with dual microwave powers. The compensation of dual microwave powers plays significant role as before. That axial line distribution of electron density was found to have agreement with the previous numerical works in the [22–24]. The two-dimension and three-dimension models were built to investigate the inner physical process of the coaxial surface linear plasma. The typical plasma linear shape along the quartz tube could be found through modelling plasma discharge process. In figure 11(b), a regular change that higher microwave power generates higher electron density is present, although there seems to be one 'bad point' in the result of 500 W/500 W (blue line in figure 11(b)). From the distribution in figure 11(c), the electron density also rose when the gas pressure going up, which might be because a number of neutral particles are more to be excited in the reaction chamber under higher pressure.
However, the uniformity of plasma under 50 Pa shows poor performance comparing with that of pressure of 30 Pa, which will be discussed in detail next. Additionally, we compare the number of electron density with the similar work from Hüber [52] and find the comparable consistency. In their work, the coaxial linear plasma was created in low pressure argon at 0.1–3 mbar and the optical emission diagnostic was also used to measure the plasma parameters. In the results, the value of the electron density in the order of 1018 m-3 was observed at the pressure of 0.6 mbar with the single input power of 120 W.
In order to satisfy with industrial application, many researchers are committed to develop large area uniform plasma source [53–56]. The higher axial uniformity is one of the key features of coaxial surface wave linear plasma presented in this paper, especially the distributions of electron density and electron excitation temperature which are important for film fabrication. Therefore, in this section, the analysis of axial uniformity in these two plasma parameters is presented.
For exhibiting conveniently, the concept of relative deviation from statistics could be introduced to indicate the character of plasma homogeneity. The relative deviation is marked as
φ=data-AA×100% | (8) |
herein, 'data' is the value of electron density or electron excitation temperature for each specified experiment point and A is the arithmetic average of these 'data'. After calculating through equation (8) for all data on electron density and electron excitation temperature we obtained before, the distributions of relative deviation are shown in figure 12.
The distinction between behavior of plasma supplied by single microwave power and dual microwave powers is revealed in evidence in figures 12(a) and (b). The relative deviations of electron density and electron excitation temperature along the axial direction have the span almost 70% and 40% under the single microwave input, which are larger than the 25% and 20% of situation under dual microwave powers input respectively. In figures 12(c) and (d), the promotion of microwave power input narrows the range of relative deviation, no matter of electron density or electron excitation temperature.
As mentioned before, the axial uniformity performs great under low pressure on coaxial surface wave linear plasma device, and the fluctuation of electron density will be happened even in the change of 20 Pa which is shown in figure 12(e). However, the relative deviation seems to be lower in electron excitation temperature under 50 Pa. As far as my knowledge is concerned, that might be caused by decreasing mean free path between particles under higher pressure, which leads to energy transfer uniformly and quickly.
In figure 13, a short summary of uniformity analysis under four typical experimental conditions is shown as column chart. The uniform coefficient [57] is utilized for evaluating the plasma axial uniformity, which is calculated from the following equation:
uniformcoefficient=φmax-φmin | (9) |
here, the
In conclusion, the coaxial surface wave linear plasma device with length over 600 mm supplied by 2.45 GHz microwave generator is developed. Different parameters of argon plasma are diagnosed through optical emission spectroscopy under low pressure. Boltzmann plot method with clear and high-resolution spectral lines of Ar atoms is used for electron excitation temperature determination. The spectra of OH (
Finally, the axial uniformity of electron density and electron excitation temperature is studied to find regulation. The uniform coefficient could be narrowed down around 40% and 22% in electron density and electron temperature respectively with the compensation of dual microwave powers input from two ends. The increasing of both power strength and gas pressure improves the uniform performance of electron excitation temperature by around 10% and 3%, respectively. However, the uniformity of electron density is ameliorated with microwave power rising but reduced with higher gas pressure. In general, the uniformity of coaxial surface wave linear plasma makes a good performance and could be controlled through adjusting microwave power and pressure.
Afterwards, the material treatment experiments such as carbon film deposition will be implemented through the coaxial surface wave linear plasma source platform. The work and results in this paper are helpful to determine the plasma parameters in our device and optimize the uniformity.
[1] |
Tian Z H et al 2022 Plasma Sci. Technol. 24 084007 doi: 10.1088/2058-6272/ac78ca
|
[2] |
Wan X et al 2021 At. Spectrosc. 42 294 doi: 10.46770/AS.2021.608
|
[3] |
Liang J H et al 2023 J. Photochem. Photobiol. B: Biol. 244 112719 doi: 10.1016/j.jphotobiol.2023.112719
|
[4] |
Sanginés R et al 2015 Spectrochim Acta Part B: At. Spectrosc. 110 139 doi: 10.1016/j.sab.2015.06.012
|
[5] |
Pérez-Rodríguez M et al 2020 Food Chem. 331 127051 doi: 10.1016/j.foodchem.2020.127051
|
[6] |
Palya A et al 2019 Int. J. Heat Mass Transfer 143 118610 doi: 10.1016/j.ijheatmasstransfer.2019.118610
|
[7] |
Bai Y et al 2020 Spectrochim. Acta Part B: At. Spectrosc. 168 105851 doi: 10.1016/j.sab.2020.105851
|
[8] |
Piepmeier E H and Malmstadt H V 1969 Anal. Chem. 41 700 doi: 10.1021/ac60275a014
|
[9] |
Hai R et al 2014 Fus. Eng. Des. 89 2435 doi: 10.1016/j.fusengdes.2014.04.065
|
[10] |
Stratis D N, Eland K L and Angel S M 2000 Appl. Spectrosc. 54 1270 doi: 10.1366/0003702001951174
|
[11] |
St-Onge L, Detalle V and Sabsabi M 2002 Spectrochim. Acta Part B: At. Spectrosc. 57 121 doi: 10.1016/S0584-8547(01)00358-5
|
[12] |
Scaffidi J et al 2003 Appl. Opt. 42 6099 doi: 10.1364/AO.42.006099
|
[13] |
Sattmann R, Sturm V and Noll R 1995 Phys. D: Appl. Phys. 28 2181 doi: 10.1088/0022-3727/28/10/030
|
[14] |
Wang Y et al 2016 Plasma Sci. Technol. 18 1192 doi: 10.1088/1009-0630/18/12/09
|
[15] |
Wang J G et al 2017 Appl. Phys. B 123 131 doi: 10.1007/s00340-017-6709-8
|
[16] |
Zhang D H et al 2018 Phys. Plasmas 25 063112 doi: 10.1063/1.5024734
|
[17] |
Forsman A C et al 2005 J. Appl. Phys. 98 033302 doi: 10.1063/1.1996834
|
[18] |
Mukherjee P, Chen S D and Witanachchi S 1999 Appl. Phys. Lett. 74 1546 doi: 10.1063/1.123611
|
[19] |
Mao X L et al 2005 Spectrochim. Acta Part B: At. Spectrosc. 60 960 doi: 10.1016/j.sab.2005.06.012
|
[20] |
Babushok V I et al 2006 Spectrochim. Acta Part B: At. Spectrosc. 61 999 doi: 10.1016/j.sab.2006.09.003
|
[21] |
Scaffidi J, Angel S M and Cremers D A 2006 Anal. Chem. 78 24 doi: 10.1021/ac069342z
|
[22] |
De Giacomo A et al 2007 Spectrochim. Acta Part B: At. Spectrosc. 62 721 doi: 10.1016/j.sab.2007.06.008
|
[23] |
Wang J X et al 2022 J. Anal. At. Spectrom. 37 1722 doi: 10.1039/D2JA00105E
|
[24] |
Ranjbar O A, Lin Z B and Volkov A N 2020 Appl. Phys. A 126 355 doi: 10.1007/s00339-020-03504-7
|
[25] |
Povarnitsyn M E and Levashov P R 2019 Appl. Phys. A 125 688 doi: 10.1007/s00339-019-2987-9
|
[26] |
Nosrati Y et al 2020 Phys. Plasmas 27 023301 doi: 10.1063/1.5132804
|
[27] |
Bulgakova N M and Bulgakov A V 2001 Appl. Phys. A 73 199 doi: 10.1007/s003390000686
|
[28] |
Chen Z Y and Bogaerts A 2005 J. Appl. Phys. 97 063305 doi: 10.1063/1.1863419
|
[29] |
Wang J X et al 2022 Plasma Sci. Technol. 24 035005 doi: 10.1088/2058-6272/ac401a
|
[30] |
Gusarov A V, Gnedovets A G and Smurov I 2000 J. Appl. Phys. 88 4352 doi: 10.1063/1.1286175
|
[31] |
Mao X L and Russo R E 1996 Appl. Phys. A: Mater. Sci. Process. 64 1 doi: 10.1007/s003390050437
|
[32] |
Bogaerts A et al 2003 Spectrochim. Acta Part B: At. Spectrosc. 58 1867 doi: 10.1016/j.sab.2003.08.004
|
[33] |
Oumeziane A A, Liani B and Parisse J D 2014 Phys. Plasmas 21 023507 doi: 10.1063/1.4864647
|
[34] |
Gautier C et al 2005 Spectrochim. Acta Part B: At. Spectrosc. 60 792 doi: 10.1016/j.sab.2005.05.006
|
[1] | Zilu ZHAO (赵紫璐), Dezheng YANG (杨德正), Wenchun WANG (王文春), Hao YUAN (袁皓), Li ZHANG (张丽), Sen WANG (王森). Volume added surface barrier discharge plasma excited by bipolar nanosecond pulse power in atmospheric air: optical emission spectra influenced by gap distance[J]. Plasma Science and Technology, 2018, 20(11): 115403. DOI: 10.1088/2058-6272/aac881 |
[2] | Gao ZHAO (赵高), Wanying ZHU (朱婉莹), Huihui WANG (王慧慧), Qiang CHEN (陈强), Chang TAN (谭畅), Jiting OUYANG (欧阳吉庭). Study of axial double layer in helicon plasma by optical emission spectroscopy and simple probe[J]. Plasma Science and Technology, 2018, 20(7): 75402-075402. DOI: 10.1088/2058-6272/aab4f1 |
[3] | Yong WANG (王勇), Cong LI (李聪), Jielin SHI (石劼霖), Xingwei WU (吴兴伟), Hongbin DING (丁洪斌). Measurement of electron density and electron temperature of a cascaded arc plasma using laser Thomson scattering compared to an optical emission spectroscopic approach[J]. Plasma Science and Technology, 2017, 19(11): 115403. DOI: 10.1088/2058-6272/aa861d |
[4] | WU Zhonghang (吴忠航), LIANG Rongqing (梁荣庆), Masaaki NAGATSU (永津雅章), CHANG Xijiang (昌锡江). The Characteristics of Columniform Surface Wave Plasma Excited Around a Quartz Rod by 2.45 GHz Microwaves[J]. Plasma Science and Technology, 2016, 18(10): 987-991. DOI: 10.1088/1009-0630/18/10/04 |
[5] | LAN Hui (兰慧), WANG Xinbing (王新兵), ZUO Duluo (左都罗). Time-Resolved Optical Emission Spectroscopy Diagnosis of CO2 Laser-Produced SnO2 Plasma[J]. Plasma Science and Technology, 2016, 18(9): 902-906. DOI: 10.1088/1009-0630/18/9/05 |
[6] | CHEN Dan (陈聃), ZENG Xinwu (曾新吾), WANG Yibo (王一博). The Optical Diagnosis of Underwater Positive Sparks and Corona Discharges[J]. Plasma Science and Technology, 2014, 16(12): 1100-1105. DOI: 10.1088/1009-0630/16/12/04 |
[7] | Panagiotis SVARNAS. Vibrational Temperature of Excited Nitrogen Molecules Detected in a 13.56 MHz Electrical Discharge by Sheath-Side Optical Emission Spectroscopy[J]. Plasma Science and Technology, 2013, 15(9): 891-895. DOI: 10.1088/1009-0630/15/9/11 |
[8] | LI Cong (李聪), ZHANG Jialiang (张家良), YAO Zhi (姚志), WU Xingwei (吴兴伟), et al.. Diagnosis of Electron, Vibrational and Rotational Temperatures in an Ar/N 2 Shock Plasma Jet Produced by a Low Pressure DC Cascade Arc Discharge[J]. Plasma Science and Technology, 2013, 15(9): 875-880. DOI: 10.1088/1009-0630/15/9/08 |
[9] | CHEN Zhaoquan (陈兆权), LIU Minghai (刘明海), HU Yelin (胡业林), ZHENG Xiaoliang (郑晓亮), LI Ping (李平), XIA Guangqing (夏广庆). Character Diagnosis for Surface-Wave Plasmas Excited by Surface Plasmon Polaritons[J]. Plasma Science and Technology, 2012, 14(8): 754-758. DOI: 10.1088/1009-0630/14/8/13 |
[10] | H. Martínez, O. Flores, J. C. Poveda, B. Campillo. Asphaltene Erosion Process in Air Plasma: Emission Spectroscopy and Surface Analysis for Air-Plasma Reactions[J]. Plasma Science and Technology, 2012, 14(4): 303-311. DOI: 10.1088/1009-0630/14/4/07 |
1. | Xie, Y., Jiang, Q., Gao, Y. et al. Temperature prediction of high-temperature and high-enthalpy plasma generators based on machine learning. Physics of Plasmas, 2025, 32(1): 013504. DOI:10.1063/5.0242129 |
2. | Niu, Y., Bao, W., Liu, D. et al. Emission spectroscopy diagnosis and discharge characteristics distribution analysis of high-frequency, high-enthalpy inductive coupling plasma generator. Vacuum, 2024. DOI:10.1016/j.vacuum.2023.112847 |
3. | Jiao, X., Tao, J., Sun, H. et al. Prediction and Analysis of Acoustic Displacement Field Using the Method of Neural Network. Communications in Computer and Information Science, 2024. DOI:10.1007/978-981-99-8126-7_11 |
4. | Zhou, B., Wu, X., Zeng, Y.-K. et al. Experimental investigation on the purification performance of particle and planktonic bacteria in the human body micro-environment using low-temperature plasma. Journal of Cleaner Production, 2023. DOI:10.1016/j.jclepro.2022.135577 |
Parameters | Information and values |
Frequency and mode | 2.45 GHz with continuous wave mode |
Powers | Dual: 300 W/300 W, 400 W/400 W, 500 W/500 W |
Single: 600 W | |
Reflection | < 0.1% |
Pressure | 30 Pa, 50 Pa |
Basic pressure | 0.0133 Pa |
Gas | Argon (99.9%) |